pH对混凝超滤组合工艺性能的影响  

Effects of p H on performance of combined process of coagulation and ultrafiltration

作　　者：童少磊[1] 孙昕[1] 陈益清[2] 尹娟[2] 

机构地区：[1]西安建筑科技大学环境与市政工程学院,西安710055 [2]深圳职业技术学院建筑与环境工程学院,深圳518055

出　　处：《环境工程学报》2016年第4期1713-1718,共6页Chinese Journal of Environmental Engineering

基　　金：国家水体污染控制与治理科技重大专项(2009ZX07423-003);广东省科技计划项目(2012B010500031);深圳市科技研发资金基础研究计划项目(JC201105201234A)

摘　　要：在聚合氯化铝(PACl)投加量为4 mg/L条件下,通过调节原水的初始p H值,考察p H条件对混凝超滤组合工艺的净水性能及膜污染的影响。结果表明:当p H为7.5时,组合工艺对COD_(Mn)、UV_(254)、DOC的去除率分别为40.2%、35.4%和36.1%;当p H降至4.5时,对应的去除率分别增加至52.9%、52.1%和42.0%。酸性条件下,膜池内絮体的分形维数大,絮体结构密实,膜污染速率较快;当p H等于4.5时,絮体分形维数为1.75±0.15,尺寸大于500μm的絮体数占总絮体数的9%。中性及偏碱性条件下,絮体分形维数小,絮体结构松散多枝,膜污染速率缓慢;当p H等于7.5时,絮体分形维数为1.37±0.05,尺寸大于500μm的絮体占65%。针对该水库的水质状况,控制原水p H为7.5有利于混凝超滤膜组合装置的运行。The effects of p H on the purification performance and membrane fouling of a combined coagulation-ultrafiltration process were investigated by adjusting the p H of raw water to different values under the polyaluminum chloride（ PACl） dosage of 4 mg / L. The experimental results showed that the removal rates of chemical oxygen demand（ COD_（Mn））,UV_（254）,and dissolved organic carbon（ DOC） from raw water at a p H of 7. 5 were40. 2%,35. 4%,and 36. 1%,respectively. These removal rates for raw water at a p H of 4. 5 increased to52. 9%,52. 1%,and 42. 0%,respectively. The fractal dimensions of flocs were relatively high,the structures were dense,and the membrane fouling was quick under the acidic conditions of raw water. The fractal dimensions of flocs were 1. 75 ± 0. 15 and the percent of flocs with a size range over 500 μm was 9% under a p H of 4. 5. Yet the fractal dimensions of flocs were low,the structures were highly-branched and loosely-bound,and the membrane fouling was relatively slow under neutral and alkaline conditions. The fractal dimensions of flocs were 1. 37± 0. 05 and the percent of flocs with a size range over 500 μm was 65% under a p H of 7. 5. According to the water quality conditions of the reservoir,it is beneficial to the operation of the combined coagulation-ultrafiltration system to control the p H of raw water at a level of 7. 5.

关 键 词：超滤 PH 分形维数 絮体结构 膜污染 

分 类 号：X703[环境科学与工程—环境工程] TU991[建筑科学—市政工程]