TiO_2光催化型抗菌陶瓷的制备及其性能研究  

Investigation on the Preparation and Properties of the TiO_2 Photocatalyst Anti-Bacterial Ceramic

作　　者：贺鹏[1] 戴武斌[2] 饶培文 曾令可[2] 王慧[2] 程小苏[2] 

机构地区：[1]湖南出入境检验检疫局,长沙410000 [2]华南理工大学材料科学与工程学院,广州510640 [3]广东道氏技术股份有限公司,佛山528021

出　　处：《中国陶瓷》2016年第4期24-28,共5页China Ceramics

基　　金：国家自然科学基金资助项目(50676033);中央高校基本科研业务费资助项目(2009ZM0174)

摘　　要：研究了用溶胶凝胶法制备锐钛矿型Ti O_2光催化剂并使用La^(3+)、Si^(4+)等阳离子进行掺杂改性。XRD图谱表明,在550℃下煅烧2 h可以得到晶形较为完整的锐钛矿Ti O_2并且掺杂改性后,晶粒大小呈现出明显的细化。同时,以罗丹明B为目标降解物,考察了Ti O_2光催化性能并以此来表征其抗菌能力。结果表明,La^(3+)、Si^(4+)掺杂改性后的Ti O_2具有较好的光催化性能;对于不同浓度的阴离子对光催化性能的影响,发现硫酸根(氯)离子团促进(抑制)了光催化反应,而硝酸根离子则无明显影响。且随着阴离子浓度的降低,影响作用也相应减小。最后,利用浸渍提拉法在瓷砖表面制备了Ti O_2薄膜,以光催化降解罗丹明B作为评价其抗菌性能指标,发现其仍保持有好的光催化性能。Sol-gel method was adopted to prepare anatase-Ti O_2 photocatalyst and the anatase-Ti O_2 was doped with La^（3＋） or Si^（4＋） ion. XRD patterns indicate that the perfect crystal of anatase Ti O_2 was obtained after calcining the sample at 550 ℃ for 2 h. With La^（3＋） or Si^（4＋） ion doping, the Ti O_2 grains were obviously refined. Using Rhodamine B（Rh-B） as the model pollutant, the photocatalytic properties of Ti O_2 were studied to characterize its antimicrobial ability and the experimental results show that the La^（3＋） or Si^（4＋） doped Ti O_2 has a good photocatalytic property. The influence of anion with different concentrations on the photocatalytic properties indicates that SO42-（Cl-） accelerates（restrains） the reaction while NO3- has no obvious influence on the reaction. As the decrease of anion concentration, the relative influence was also reduced. Finally, the Ti O_2 films were produced on the tiles by the dipping method. Using Photocatalytic degradation of the Rh-B as the evaluation indicator of antimicrobial properties shows its good photocatalytic performance.

关 键 词：二氧化钛 光催化 掺杂 

分 类 号：TQ174.758.11[化学工程—陶瓷工业]