三聚表面活性剂的研究进展  

Research work development with respect to trimeric surfactants

作　　者：廖学明[1,2] 高志农[1,2] 夏衍[1,2] 卫婉英 周航[1,2] 潘晨晨[1,2] 

机构地区：[1]武汉大学化学与分子科学学院,湖北武汉430072 [2]武汉大学生物医用高分子材料教育部重点实验室,湖北武汉430072

出　　处：《日用化学工业》2016年第4期231-237,共7页China Surfactant Detergent & Cosmetics

基　　金：中央高校基本科研业务费专项资金资助项目(2012203020211)

摘　　要：综述了三聚表面活性剂的分类、合成方法、结构对性能的影响以及应用。根据亲水头基的电性不同,三聚表面活性剂可分为阳离子型、阴离子型、非离子型和两性离子型4类。根据其结构特点,设计了不同亲水头基、不同中间连接基团和不同尾链的三聚表面活性剂的合成路线。最后介绍了三聚表面活性剂的性能及其在纳米材料的制备、乳液聚合等领域的应用,并对其未来的发展趋势进行了展望。Classification and synthesis method of trimeric surfactans as well as effect of structure on their performance and applications were summarized. According to the different electrical property of hydrophilic head groups of trimeric surfactants,they can be classified into four classes,as cationic type,anionic type,nonionic type and amphoteric type. Based upon their structure characteristics,designs of various synthesis routes,for preparing trimeric surfactants with different head groups,different space groups and different tail chains were described. Finally,performance of trimeric surfactants and their applications in various domains,such as preparation of nanomaterials,emulsion polymerization and so on were introduced. The future trend of development in this field was predicted as well.

关 键 词：三聚表面活性剂 合成方法 结构 性能 

分 类 号：TQ423[化学工程]