用于甲醇脱水体系的催化功能材料的合成及性质研究  

Synthesis and Catalytic Properties of Functional Materials for Methanol Dehydration System

作　　者：周付江[1] 薛韩[1] 鲁聪颖 龚舒哲[1] 初洪涛[1] 董海博 

机构地区：[1]大庆师范学院,黑龙江大庆163712

出　　处：《化工时刊》2016年第2期16-18,54,共4页Chemical Industry Times

基　　金：大庆市指导性科技计划项目(szdfy-2015-67);大庆师范学院科学研究基金项目(11ZR02)

摘　　要：本文介绍了多金属氧酸盐的合成方法以及微孔金属氧酸盐的发展概况,研究了在常温水溶液的条件下,以多金属氧酸盐为基础的手性化合物的合成方法。参照和研究了参照化合物X-射线单晶衍射的测定结果,对化合物的合成方法、结构和性质进行了研究,并将其作为催化剂对甲醇生成二甲醚反应体系进行应用,实验结果表明这类杂化物具有较强的催化性能。In this paper,the synthesis of POMs and development before microporous polyoxometalates were mentioned,and the synthesis under the conditions of room temperature water to polyoxometalate- based chiral compounds was studied. The X- ray diffraction,the structure and the properties of the compounds were studied as catalysts for methanol and dimethyl ether reaction volume for application,the experimental results showed that this type of hybrids have a promising properties in catalysis.

关 键 词：多金属氧酸盐(POMs) 金属有机框架(MOFs) 催化剂 合成 

分 类 号：O643.36[理学—物理化学] TQ223.24[理学—化学]