新型油酸基咪唑啉酰胺对A3碳钢的缓蚀性能研究  

INHIBITION PROPERTY OF OLEIC IMIDAZOLINE AMIDE FOR A3 MILD STEEL CORROSION

作　　者：张磊[1,2] 项玉芝[1,2] 周玉路[1,2] 夏道宏[2] 

机构地区：[1]中国石油大学(华东)理学院,山东青岛266580 [2]中国石油大学(华东)重质油国家重点实验室

出　　处：《石油炼制与化工》2016年第5期89-94,共6页Petroleum Processing and Petrochemicals

摘　　要：针对高酸原油加工中分馏塔顶循环回流(简称顶循)系统腐蚀加剧的现状,对自合成的新型油酸基咪唑啉酰胺(EYP)的缓蚀性能进行了研究。采用失重法评价缓蚀剂EYP在模拟顶循油体系中的缓蚀性能,考察了EYP的添加量和腐蚀体系温度对其缓蚀效率的影响,并采用电化学方法对缓蚀机理进行了探讨,采用SEM对碳钢表面的腐蚀形貌进行了分析。结果表明:EYP在顶循油模拟体系中对A3碳钢具有优良的缓蚀性能;随着腐蚀体系中EYP添加量的增大,缓蚀效率先增大然后略有降低;温度对EYP的缓蚀效率影响较小,随着温度升高,EYP的缓蚀效率略有降低;EYP在金属表面的吸附包括化学吸附和物理吸附,呈一种有序化的状态;EYP是一种能同时抑制阴极和阳极反应的高效"混合型缓蚀剂"。The corrosion inhibition performance of a newly synthesized oleic acid imidazoline amide（ EYP）for the mild steel in overhead circulating reflux system of fractionation tower at different amount of EYP and system temperature was investigated by weight loss method. The surface morphologies of mild steel specimens were observed by scanning electron microscope（ SEM）. The electrochemical impedance spectroscopy（ EIS） was used to study the corrosion mechanism. The results demonstrate that EYP can effectively protect A3 mild steel from corrosion in simulative top cycle oil. The inhibition efficiency of EYP increases firstly and then decreases mildly with the increase of EYP concentration,and the temperature changes only have slightly influence on the corrosion efficiency. EIS results and the calculated kinetic parameters reveal that the adsorption of EYP on the steel surface includes physical adsorption and chemical adsorption,showing an ordering state,and that EYP is a mixed-type inhibitor retarding reactions on anodic or cathodic electrode.

关 键 词：油酸基咪唑啉酰胺 缓蚀性能 A3碳钢 分馏塔 顶循环回流 

分 类 号：TE986[石油与天然气工程—石油机械设备]