水溶性氮杂环卡宾金属化合物的催化应用  

Study on catalytic application of water soluble N-heterocyclic carbene metal complex as organocatalysts

作　　者：崔美丽[1] 郭芳杰[1] 周明东[1] 

机构地区：[1]辽宁石油化工大学化学与材料科学学院,抚顺113001

出　　处：《科技导报》2016年第8期45-53,共9页Science & Technology Review

基　　金：国家自然科学基金项目(21101085);国家科技支撑计划项目(2012BAF03 B00)

摘　　要：水溶性氮杂环卡宾金属化合物因催化效率高、选择性和稳定性较好及应用范围广,成为有机合成中重要的催化剂,在选择性催化有机反应中发挥着重要作用。本文综述近年来水溶性氮杂环卡宾金属配合物的主要类型、合成方法及其在金属有机催化反应中的研究进展。In recent years,water-soluble N-heterocyclic carbene metal complex have been widely used in organic synthesis due to its high catalytic efficiency,good selectivity and stability.It is playing an increasingly important role in the selective catalytic organic reactions and has aroused great concern.This paper reviews the types,the synthesis and the application of research results of water- soluble Nheterocyclic carbene metal compound in the field of organometallic catalytic chemistry,and its prospect is also depicted.

关 键 词：水溶性 氮杂环卡宾 催化反应 

分 类 号：O643.36[理学—物理化学]