含氢化诺卜基的叔胺类化合物的合成与结构分析  

The Synthesis and Structural Analysis of Hydronopyl Tertiary Amine Compounds

作　　者：陈金珠[1] 肖转泉[2] 徐丽锋 王宗徳 韩招久[4] 

机构地区：[1]江西农业大学理学院,江西南昌330045 [2]江西师范大学化学化工学院,江西南昌330027 [3]江西农业大学林学院,江西南昌330045 [4]南京军区军事医学研究所,江苏南京210002

出　　处：《江西师范大学学报（自然科学版）》2016年第2期179-182,共4页Journal of Jiangxi Normal University(Natural Science Edition)

基　　金：国家自然科学基金(31060101);江西省教育厅科学技术项目(GJJ150427);南京市科技计划(201301052)资助项目

摘　　要：由cis-氢化诺卜醇与亚硫酰氯反应制得cis-氢化诺卜基氯,再分别与二甲胺、二乙胺、二正丙胺、二正丁胺、六氢吡啶、吗啉等仲胺反应,合成了6种cis-氢化诺卜基的叔胺,产品GC纯度达95%以上.通过红外光谱、核磁共振谱和质谱分析表征了它们的结构.Cis-hydronopyl chloride was synthesized by cis-hydronopol and thionyl chloride. Then six kinds of cishydronopyl tertiary amine compounds were synthesized from the reaction of hydronopyl chloride with dimethylamine,diethylamin,diisopropylamin,dipropylamine,dibutylamine,hexahydropyridine and morpholine respectively. The GC content of the products were over 95% and their structures were characterized and analyzed by IR,NMR and MS methods.

关 键 词：氢化诺卜醇 氢化诺卜基氯 叔胺 合成 结构分析 

分 类 号：TQ351[化学工程] O621[理学—有机化学]