RTV-2缩合型硅橡胶胶粘剂的固化研究  

Curing Research of RTV-2Condensed Type Silicone Rubber Adhesive

作　　者：付晓燕[1] 罗宏[1,2] 李新跃[1,2] 丁申影 

机构地区：[1]四川理工学院材料与化学工程学院,四川自贡643000 [2]材料腐蚀与防护四川省高校重点实验室,四川自贡643000

出　　处：《河北师范大学学报（自然科学版）》2016年第2期149-152,共4页Journal of Hebei Normal University：Natural Science

基　　金：四川省重点实验室基金(2014CL11)

摘　　要：选用羟基封端的聚二甲基硅氧烷(PMDS)、MQ硅树脂和正硅酸乙酯为A组分,二丁基二月桂酸锡、钛酸丁酯和硼酸三丁酯为B组分,在室温条件下2组分混合固化交联.利用单因素试验得到各因素对有机硅胶粘剂粘接性强度的影响趋势;再以邵氏A型硬度计测试的硬度值和硫化橡胶与金属粘接的拉伸剪切强度为正交试验指标,分析得出影响胶粘剂固化的因素.综合性能较好的RTV-2硅橡胶的固化体系配方:107胶25g,MQ硅树脂2.5g,正硅酸乙酯2g,钛酸丁酯0.75g,硼酸三丁酯0.75g,二丁基二月桂酸锡0.375g.MQ硅树脂的加入能够提高RTV-2硅橡胶的硬度,钛酸丁酯的用量对硅橡胶与金属粘接的剪切强度影响最大.In this paper,the hydroxy-terminated PMDS,MQ silicone resin and TEOS were chosen as part A,and the dibutyltin dilaurate,tetrabutyl titanate and tributyl borate were used as part B.At room temperature,the cross-linking solidity was occurred by mixing A and B.The factors influencing on the adhesion strength of organic silicone adhesive were obtained by single factor experiment.Shore A hardness values and vulcanized rubber to metal bonding tensile shear strength were used as orthogonal test indicators,to determine the influence factors of curing silicone rubber adhesive.Experimental results show that the better overall performance of RTV-2can be made from 25 g 107gum,MQ silicone resin 2.5g,TEOS 2g,tetra-n-butyl 0.75 g,tributyl borate 0.75 g,dibutyl tin dilaurate 0.375 g.MQ silicone resin can be supplemented with RTV-2silicone resin.The amount of tetrabutyl titanate to the adhesive properties of silicone rubber was the biggest one of effect factors.

关 键 词：RTV-2 缩合型 胶粘剂 最佳配方 

分 类 号：TQ333.93[化学工程—橡胶工业]