Emissions from the combustion of eucalypt and pine chips in a fluidized bed reactor  

作　　者：E.D.Vicente L.A.C.Tarelho E.R.Teixeira M.Duarte T.Nunes C.Colombi V.Gianelle G.O.da Rocha A.Sanchez de la Campa C.A.Alves 

机构地区：[1]Centre for Environmental and Marine Studies,Department of Environment and Planning,University of Aveiro [2]Regional Centre for Air Quality Monitoring,Environmental Monitoring Sector ARPA [3]Federal University of Bahia,Chemical Institute,40170-290,Campus de Ondina [4]Centre for Research in Sustainable Chemistry (CIQSO),Joint Research Unit to CSIC "Atmospheric Pollution",University of Huelva,Campus El Carmen

出　　处：《Journal of Environmental Sciences》2016年第4期246-258,共13页环境科学学报（英文版）

基　　金：supported by the Portuguese Foundation for Science and Technology through the projects Biom Ash Tech-Ash impacts during thermo-chemical conversion of biomass(No.PTDC/AAC-AMB/116568/2010-FCOMP-01-0124-FEDER-019346) and BIOEMI-Contribution of biomass combustion to air pollutant emissions(No.PTDC/AMB/65706/2006);European Commission through the project AIRUSE-Testing and development of air quality mitigation measures in Southern Europe(No.LIFE 11 ENV/ES/000584)

摘　　要：Interest in renewable energy sources has increased in recent years due to environmental concerns about global warming and air pollution,reduced costs and improved efficiency of technologies.Under the European Union（EU）energy directive,biomass is a suitable renewable source.The aim of this study was to experimentally quantify and characterize the emission of particulate matter（PM（2.5））resulting from the combustion of two biomass fuels（chipped residual biomass from pine and eucalypt）,in a pilot-scale bubbling fluidized bed（BFB）combustor under distinct operating conditions.The variables evaluated were the stoichiometry and,in the case of eucalypt,the leaching of the fuel.The CO and PM（2.5）emission factors were lower when the stoichiometry used in the experiments was higher（0.33±0.1 g CO/kg and 16.8±1.0 mg PM（2.5）/kg,dry gases）.The treatment of the fuel by leaching before its combustion has shown to promote higher PM（2.5）emissions（55.2±2.5 mg/kg,as burned）.Organic and elemental carbon represented 3.1 to 30 wt.% of the particle mass,while carbonate（CO3^（2-））accounted for between 2.3 and 8.5 wt.%.The particulate mass was mainly composed of inorganic matter（71% to 86% of the PM（2.5）mass）.Compared to residential stoves,BFB combustion generated very high mass fractions of inorganic elements.Chloride was the water soluble ion in higher concentration in the PM（2.5）emitted by the combustion of eucalypt,while calcium was the dominant water soluble ion in the case of pine.Interest in renewable energy sources has increased in recent years due to environmental concerns about global warming and air pollution,reduced costs and improved efficiency of technologies.Under the European Union（EU）energy directive,biomass is a suitable renewable source.The aim of this study was to experimentally quantify and characterize the emission of particulate matter（PM（2.5））resulting from the combustion of two biomass fuels（chipped residual biomass from pine and eucalypt）,in a pilot-scale bubbling fluidized bed（BFB）combustor under distinct operating conditions.The variables evaluated were the stoichiometry and,in the case of eucalypt,the leaching of the fuel.The CO and PM（2.5）emission factors were lower when the stoichiometry used in the experiments was higher（0.33±0.1 g CO/kg and 16.8±1.0 mg PM（2.5）/kg,dry gases）.The treatment of the fuel by leaching before its combustion has shown to promote higher PM（2.5）emissions（55.2±2.5 mg/kg,as burned）.Organic and elemental carbon represented 3.1 to 30 wt.% of the particle mass,while carbonate（CO3^（2-））accounted for between 2.3 and 8.5 wt.%.The particulate mass was mainly composed of inorganic matter（71% to 86% of the PM（2.5）mass）.Compared to residential stoves,BFB combustion generated very high mass fractions of inorganic elements.Chloride was the water soluble ion in higher concentration in the PM（2.5）emitted by the combustion of eucalypt,while calcium was the dominant water soluble ion in the case of pine.

关 键 词：Biomass Combustion Fluidized bed PM2.5emissions Chemical composition 

分 类 号：X701[环境科学与工程—环境工程]