普鲁士蓝类钠离子电池正极材料研究进展  

Progress in prussian blue in sodium ion cathode material

作　　者：杨旸[1] 严小敏[1] 杨德志[1] 王红[1,2] 廖小珍[1,2] 马紫峰[1,2] 

机构地区：[1]上海交通大学化学化工学院,上海电化学能源器件工程技术研究中心,上海200240 [2]上海中聚佳华电池科技有限公司中聚电池研究院,上海200241

出　　处：《储能科学与技术》2016年第3期303-308,共6页Energy Storage Science and Technology

基　　金：国家自然科学基金(21336003,21573147,21506123);国家重点基础研究发展计划(973)(2014CB239703);上海市科委(15ZR1422300,14DZ2250800)项目

摘　　要：近年来,随着储能技术的快速发展,钠离子电池因为资源丰富、环境友好、成本低廉,成为电化学储能技术研究热点;而其正极材料是制约钠离子电池应用的关键因素之一。普鲁士蓝类正极材料具有开框架结构,有利于钠离子的快速迁移,这种结构使其具有良好的电化学性能。本文简要介绍了普鲁士蓝类化合物及其复合材料在水体系和有机体系钠离子电池中的研究情况。普鲁士蓝类正极材料由于制备工艺简单,结构稳定,是极有潜力的钠离子储能材料。In recent years, with the rapid development of energy storage technology,sodium ion batteries have attracted a great attention due to the low-cost, environment friendly, and abundant resource of sodium. The cathode material is one of the key factor of restricting the sodium ion battery application. Prussian blue and its analogues（PBAs） have been intensely studied as promising cathode materials for sodium ion batteries due to their rigid open framework which benefits Na＋ insertion/extraction. In this review, we briefly summarize the research progress of PBAs and their composite materials in the water system and organic system sodium ion batteries. PBAs are promising cathode materials due to their simple preparation, stable structure, and superior electrochemical performance.

关 键 词：钠离子电池 正极材料 普鲁士蓝类材料 

分 类 号：TM53[电气工程—电器]