Capacitive Performances of Reduced Graphene Oxide Hydrogel Prepared by Using Sodium Hypophosphite as Reducer  

作　　者：Cuixian Liu Gaoyi Han Yunzhen Chang Yaoming Xiao Yanping Li Miaoyu Li Haihan Zhou 

机构地区：[1]The Institute of Molecular Science, Key Laboratory of Shanxi Province for Energy Conversion and Storage Materials, Taiyuan, Shanxi 030006, China

出　　处：《Chinese Journal of Chemistry》2016年第1期89-97,共9页中国化学（英文版）

基　　金：Acknowledgement The authors thank the National Natural Science Foundation of China （Nos. 21574076, 21501113, 61504076 and 21407100） and Shanxi Province （No. 2014011016-1）, the Program for the Top Young and Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi （No. 02035290 1014）.

摘　　要：The hydrogels of reduced graphene oxide （rGOHGs） have been synthesized through treating GO with various concentrations of sodium hypophosphite （NaH2PO2） under hydrothermal condition. The results reveal that the structure of rGOHGs changes along with the increase of the concentration of NaH2PO2. The rGO sheets prepared with low concentration of NaH2PO2 exhibit more crimples and larger specific surface area than those prepared with high concentration of NaH2PO2. The measurements of the capacitive performances of rGOHGs reveal that the rGOHGs prepared with low concentration of NaH2PO2 possess larger specific capacitance （Cs） than that prepared with high concentration of NaH2PO2 at low cyclic voltammetry scan rates. However, the rGOHGs prepared with high concentration of NaH2PO2 possess larger Cs at high scan rates, more stability and better high-rate capability than those prepared at low concentration. It is believed that the structures and properties of rGOHGs can be adjusted by controlling the concentration of NaH2PO2 according to the requirement.The hydrogels of reduced graphene oxide （rGOHGs） have been synthesized through treating GO with various concentrations of sodium hypophosphite （NaH2PO2） under hydrothermal condition. The results reveal that the structure of rGOHGs changes along with the increase of the concentration of NaH2PO2. The rGO sheets prepared with low concentration of NaH2PO2 exhibit more crimples and larger specific surface area than those prepared with high concentration of NaH2PO2. The measurements of the capacitive performances of rGOHGs reveal that the rGOHGs prepared with low concentration of NaH2PO2 possess larger specific capacitance （Cs） than that prepared with high concentration of NaH2PO2 at low cyclic voltammetry scan rates. However, the rGOHGs prepared with high concentration of NaH2PO2 possess larger Cs at high scan rates, more stability and better high-rate capability than those prepared at low concentration. It is believed that the structures and properties of rGOHGs can be adjusted by controlling the concentration of NaH2PO2 according to the requirement.

关 键 词：graphene hydrogels NAH2PO2 electrochemical capacitors HYDROTHERMAL 

分 类 号：TQ153.12[化学工程—电化学工业] TM53[电气工程—电器]