Two Three-dimensional Terbium-1,4-benzenedicarboxylate Coordination Polymers：Syntheses,Structures,and Luminescence  

作　　者：雷倩 刘庆燕 王玉玲 陈莉莉 殷顺高 

机构地区：[1]Key Laboratory of Small Functional Organic Molecule of Ministry of Education,College of Chemistry and Chemical Engineering,Jiangxi Normal University [2]State key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences

出　　处：《Chinese Journal of Structural Chemistry》2016年第4期566-576,共11页结构化学（英文）

基　　金：Supported by the NNSFC(21361011);the Provincial Natural Science Foundation of Jiangxi(20151BAB203002);the Project of Education Department of Jiangxi Province(GJJ14235);the Open Project Program of Key Laboratory of Functional Small Organic Molecule,Ministry of Education,Jiangxi Normal University(KLFS-KF-201412)

摘　　要：Two coordination polymers with 1,4-benzenedicarboxylic acid（H2BDC） ligand, namely, [Tb3（BDC）（4.5）（H2O）（DMF）2]n （1） and [Tb2（BDC）3（H2O）2（DMF）2]n（2）, have been synthesized and characterized. Both compounds crystallize in the triclinic system, space group P1. For compound 1, a = 10.8528（5）, b = 12.2516（5）, c = 16.9031（7） A, α = 104.462（1）, β = 93.659（1）, γ = 101.404（1）°, V = 2118.1（2） A^3, Z = 2, C（42）H（34）N2O（21）Tb3, Mr = 1379.47, Dc = 2.163 g/cm^3, μ = 5.045 mm^-1, F（000） = 1326, the final R = 0.0212 and wR = 0.0570 for 8592 observed reflections with I 〉 2σ（I）. For compound 2, a = 8.547（1）, b = 10.170（1）, c = 11.192（1）A？, α = 65.531（1）, β = 71.886（1）, γ = 78.796（1）°, V = 839.2（2） A^3, Z = 1, C（30）H（30）N2O（16）Tb2, Mr = 992.40, Dc = 1.964 g/cm^3, μ = 4.257 mm^-1, F（000） = 482, the final R = 0.0220 and wR = 0.0649 for 3626 observed reflections with I 〉 2σ（I）. The compounds exhibit different structural topologies depending on the nature of templating agents in the reactions though the templating agents are not incorporated in the final solids. Compound 1 exhibits a three-dimensional（3D） framework based on the rod-shaped terbium-carboxylate building blocks constructed from linear trinuclear Tb3 units. Compound 2 has a 3D framework containing two interpenetrating pcu topological networks based on the 6-connected dinuclear Tb2 secondary building units. Photoluminescence studies show both compounds exhibit typical Tb（Ⅲ） luminescence emissions. An efficient ligand-to-Tb（Ⅲ） energy transfer is observed in the emission spectra for both compounds.Two coordination polymers with 1,4-benzenedicarboxylic acid（H2BDC） ligand, namely, [Tb3（BDC）（4.5）（H2O）（DMF）2]n （1） and [Tb2（BDC）3（H2O）2（DMF）2]n（2）, have been synthesized and characterized. Both compounds crystallize in the triclinic system, space group P1. For compound 1, a = 10.8528（5）, b = 12.2516（5）, c = 16.9031（7） A, α = 104.462（1）, β = 93.659（1）, γ = 101.404（1）°, V = 2118.1（2） A^3, Z = 2, C（42）H（34）N2O（21）Tb3, Mr = 1379.47, Dc = 2.163 g/cm^3, μ = 5.045 mm^-1, F（000） = 1326, the final R = 0.0212 and wR = 0.0570 for 8592 observed reflections with I 〉 2σ（I）. For compound 2, a = 8.547（1）, b = 10.170（1）, c = 11.192（1）A？, α = 65.531（1）, β = 71.886（1）, γ = 78.796（1）°, V = 839.2（2） A^3, Z = 1, C（30）H（30）N2O（16）Tb2, Mr = 992.40, Dc = 1.964 g/cm^3, μ = 4.257 mm^-1, F（000） = 482, the final R = 0.0220 and wR = 0.0649 for 3626 observed reflections with I 〉 2σ（I）. The compounds exhibit different structural topologies depending on the nature of templating agents in the reactions though the templating agents are not incorporated in the final solids. Compound 1 exhibits a three-dimensional（3D） framework based on the rod-shaped terbium-carboxylate building blocks constructed from linear trinuclear Tb3 units. Compound 2 has a 3D framework containing two interpenetrating pcu topological networks based on the 6-connected dinuclear Tb2 secondary building units. Photoluminescence studies show both compounds exhibit typical Tb（Ⅲ） luminescence emissions. An efficient ligand-to-Tb（Ⅲ） energy transfer is observed in the emission spectra for both compounds.

关 键 词：terbium coordination compounds luminescence templates 1 4-benzenedicarboxylate 

分 类 号：O634[理学—高分子化学]