PP/纳米SiO_2/氮磷阻燃剂复合材料的研究  

PP/nano-SiO_2/N-P Compound Flame Retardant Composites

作　　者：魏风军[1] 贾秋丽[1] 郭福全[2] 张炎斌[1] 

机构地区：[1]河南科技大学,洛阳471023 [2]洛阳理工学院,洛阳471023

出　　处：《包装工程》2016年第9期16-20,共5页Packaging Engineering

基　　金：国家自然科学基金(51105130);河南省教育厅自然科学计划(2009A460003)

摘　　要：目的研究聚丙烯复合材料的燃烧行为和纳米SiO_2含量对复合材料力学性能的影响。方法采用熔融共混方法,将聚丙烯、氮磷复配阻燃剂及表面改性的纳米SiO_2制备成聚丙烯复合材料。结果在燃烧过程中纳米SiO_2对阻燃性能有一定影响,氮磷复配阻燃剂是影响复合材料阻燃性能的关键因素。随着纳米SiO_2含量的增加,复合材料的极限氧指数先增加后降低,当纳米SiO_2质量分数为1%时,复合材料的极限氧指数最大。随着纳米SiO_2含量的增加,复合材料的拉伸、冲击、弯曲强度和弯曲模量呈现先增大后减小的现象。结论氮磷复配阻燃剂与纳米SiO_2对于复合材料有一定的协同阻燃效果。当纳米SiO_2质量分数为1%时,复合材料的阻燃及力学性能最优。This work aimed to study the burning behavior of polypropylene composites and the effect of nano-SiO2 content on the mechanical properties of the composite. By means of melt blending method,polypropylene,nitrogen and phosphorus compound flame retardant and surface modified nano-SiO2 composite materials were mixed to prepare polypropylene composites. The results showed that： in the process of combustion,nano-SiO2 had some effects on the flame retardancy,and the nitrogen and phosphorus compound flame retardant was a key factor affecting the flame retardancy of the composites. With increasing nano-SiO2 content,the limiting oxygen index of the composites first increased and then decreased. When the nano-SiO2 content was 1%,the limiting oxygen index of the composites was the maximum. With increasing Nano-SiO2 content,the tensile,impact and bending strength as well as the flexural modulus first increased and then decreased. There was a certain synergistic flame retarding effect of nitrogen and phosphorus compound flame retardant and nano-SiO2 on the composite materials. When the nano-SiO2 content was 1%,the composites with optimal flame retardancy and mechanical properties were obtained.

关 键 词：聚丙烯 纳米SIO2 氮磷复配阻燃剂 燃烧行为 力学性能 

分 类 号：TB484.9[一般工业技术—包装工程]