Re和W对铸态镍基单晶高温合金再结晶的影响  

EFFECT OF Re AND W ON RECRYSTALLIZATION OF AS-CAST Ni-BASED SINGLE CRYSTAL SUPERALLOYS

作　　者：濮晟[1,2] 谢光[2,3] 王莉[2,3] 潘智毅 楼琅洪[2] 

机构地区：[1]北京科技大学新金属材料国家重点实验室,北京100083 [2]中国科学院金属研究所,沈阳110016 [3]中国科学院金属研究所沈阳材料科学国家(联合)实验室,沈阳110016 [4]清华大学深圳研究生院,深圳518055

出　　处：《金属学报》2016年第5期538-548,共11页Acta Metallurgica Sinica

基　　金：国家自然科学基金项目50901079;国家重点基础研究发展计划项目2010CB631201;国家高技术研究发展计划项目2012AA03A513资助~~

摘　　要：对不同Re和W含量的铸态镍基单晶高温合金通过Brinell硬度计压痕变形,分别在1230～1330℃保温1 h,研究了难熔元素Re和W对合金再结晶行为的影响.结果表明,再结晶晶粒在压痕表面形成,并沿枝晶干向内扩展,晶界迁移受到枝晶间粗大g＇相和g＋g＇共晶阻碍.添加Re和W提高了铸态单晶高温合金的g＇相溶解温度和g＋g＇共晶含量,导致单晶高温合金的再结晶温度升高.热处理温度升高,各单晶高温合金的再结晶面积随着枝晶间g＇相和共晶含量的减少而增大.相同热处理温度下,由于不同成分单晶高温合金枝晶间粗大g＇相和g＋g＇共晶含量不同,不含难熔元素Re和W的单晶高温合金再结晶面积最大,含Re单晶高温合金的再结晶面积大于含W单晶高温合金,同时添加Re和W的单晶高温合金再结晶面积最小.Ni-based single crystal（SX） superalloys have been used as blades in aero-space industry and landbased applications due to their excellent high-temperature properties. However, residual strain is introduced into ascast SX superalloy blades during the manufacturing process, such as casting, grinding or shot peening, and so on.Recrystallization（RX） occurs easily during subsequent high temperature heat treatment. In previous work, it is believed that RX has detrimental effect on the mechanical properties of SX superalloy. Furthermore, in order to improve the mechanical properties, more and more refractory elements, such as W, Re, Mo, Ta, are added into SXsuperalloys. However, so far, few reports about the effect of refractory elements on the RX in as-cast SX superalloys have been available. In the present work, the effect of Re and W on the RX behavior of as-cast Ni-based SX superalloy was studied. Single crystal superalloys with different Re and W contents were annealed at 1230~1330 ℃ after indened using Brinell hardnesstester. It is found that RX grains form at the surface under indentation and grow preferentially along the dendritic cores. Subsequent growth of RX is impeded by the residual coarse g＇and g ＋g＇ eutectics in the interdendritic regions. Both the volume fraction of g ＋g＇ eutectics and g＇ solvus temperature are increased with the addition of Re and W, which are attributed to the increase of RX threshold temperature.For all SX superalloys studied in this work, RX area increases with the increase of annealing temperature due to the dissolution of g＇ and g＋g＇ eutectics. At the same annealing temperature, in comparison to Re, W shows more effect to inhibit RX growth. Additionally, SX superalloy containing both Re and W has the smallest RX area in the present experiments.

关 键 词：镍基单晶高温合金 再结晶 共晶 RE W 

分 类 号：TG132.3[一般工业技术—材料科学与工程]