多酸基高核过渡金属簇合物的性质及合成条件研究  

The Properties and Synthesis Conditions of Polyoxometalate Based Transition Metal Clusters with High Nuclear

作　　者：周付江[1] 何丹凤[1] 王圆圆[1] 初洪涛[1] 佟雪[1] 崔江婷 杨静[1] 张瑜[1] 龚舒哲[1] 董海博 

机构地区：[1]大庆师范学院,黑龙江大庆163712

出　　处：《化工时刊》2016年第3期1-4,共4页Chemical Industry Times

基　　金：大庆师范学院科学研究基金项目(11ZR02);黑龙江省大学生创新创业项目(201510235034)

摘　　要：采用常规的水热合成方法,以Keggin型多金属氧酸盐作为基本构筑单元,向其中引入过渡金属配合物,合成了具有手性功能的新型无机-有机杂化材料,并且讨论了目标化合物的合成条件与产物以及该物质的性能和结构之间的关系。The conventional hydrothermal synthesis method was used to synthesize Keggin -type polyoxometalate as the basic building blocks, and the transition metal complexes was introduced in the reaction systerm, chiral synthesis capabilities of the new inorganic - organic hybrid materials was prepared and discussed. In addition, the synthesis conditions of the target compound and the relationship between product performance and structure of the substance were discussed.

关 键 词：多金属氧酸盐 性质 条件 合成 

分 类 号：O641.4[理学—物理化学]