无溶剂法在有机锌与醛(酮)不对称加成反应中的应用  

Application of Solvent-Free Method in Asymmetic Addition Reaction of Organozinc with Aldehyde or Ketone

作　　者：杨翠凤[1,2] 刘文[3] 林双政[1,2] 徐泽刚[1,2] 陈涛[1,2] 卫天琪 李秉擘 

机构地区：[1]氟氮化工资源高效开发与利用国家重点实验室,陕西西安710065 [2]西安近代化学研究所,陕西西安710065 [3]西安建筑科技大学理学院,陕西西安710065

出　　处：《合成化学》2016年第5期464-468,共5页Chinese Journal of Synthetic Chemistry

摘　　要：综述了无溶剂法在有机锌与醛酮不对称加成反应中的应用。重点阐述了该方法在制备手性二级醇和手性三级醇中的应用。并对其未来发展进行了展望。参考文献30篇。Application of solvent-free method in asymmetric addition reaction of organozinc with aldehyde or ketone was reviewed with 30 references. Application in preparation of secondary or tertiary alcohol was introduced. Suggestions on future development of this method were proposed.

关 键 词：无溶剂法 有机锌 醛(酮)不对称加成 应用 综述 

分 类 号：O621.3[理学—有机化学]