Azopyridine-imidacloprid derivatives as photoresponsive neonicotinoids  

作　　者：Shen Li Run-Jiang Song Dong-Hui Wang Xue Tian Xu-Sheng Shao Zhong Li 

机构地区：[1]Shanghai Key Laboratory of Chemical Biology, School of Pharmacy, East China University of Science and Technology, Shanghai 200237, China [2]College of Life Science, Perking University, Beijing 100871, China

出　　处：《Chinese Chemical Letters》2016年第5期635-639,共5页中国化学快报（英文版）

基　　金：financial supported by National Natural Science Foundation of China (Nos. 21372079, 21472046);Shanghai Pujiang Program (No. 14PJD012);the Fundamental Research Funds for the Central Universities (No. 222201414015)

摘　　要：A series of imidacloprid derivatives containing an azopyridine motif as a photoswitchable functional group were designed and synthesized. The new version of photoresponsive imidacloprid analogues showed improved solubility in comparison with their azobenzene analogues. 1.2 to 2-fold activity difference was observed for these azopyridine-imidacloprids against house fly （Musca domestica） and cowpea aphid （Aphis craccivora） upon irradiation.A series of imidacloprid derivatives containing an azopyridine motif as a photoswitchable functional group were designed and synthesized. The new version of photoresponsive imidacloprid analogues showed improved solubility in comparison with their azobenzene analogues. 1.2 to 2-fold activity difference was observed for these azopyridine-imidacloprids against house fly （Musca domestica） and cowpea aphid （Aphis craccivora） upon irradiation.

关 键 词：Azopyridine Photoresponsive Imidacloprid Solubility Insecticide 

分 类 号：TQ453[化学工程—农药化工]