Electrochemical behavior and analytical detection of Imidacloprid insecticide on a BDD electrode using square-wave voltammetric method  

作　　者：Mabrouk Ben Brahim Hafedh Belhadj Ammar Ridha Abdelhedi Youssef Samet 

机构地区：[1]Electrochemistry and Environmental Laboratory, Department of Materials Engineering, National Engineering School of Sfax, University of Sfax, B.P. I 173,3038 Sfax, Tunisia

出　　处：《Chinese Chemical Letters》2016年第5期666-672,共7页中国化学快报（英文版）

基　　金：financially supported by the Tunisian Ministry of Higher Education and Scientific Research

摘　　要：A sensitive square-wave voltammetric method for the determination of lmidacloprid （IMD） was developed using electrochemically pretreated boron-doped diamond （BDD） electrode. Aqueous solutions were prepared with Confidor 200 SL as the commercial formulation of IMD. Sodium sulfate （Na2SO4） was used as supporting electrolyte. The influence of operating parameters, such as the pH of the medium, frequency, pulse amplitude, scan increment and the concentration of IMD was investigated. An irreversible cathodic peak, corresponding to the reduction oflMD is observed at 1.21 V （vs. SCE） and the electrode reaction was controlled by adsorption. Under optimized conditions, the square-wave reduction peak current was linear over the concentration range of （30-200 μmol L 1） with a detection and quantification limits of 8.60 μmol L 1 and 28.67 μmol L 1, respectively. The results were compared with spectrophotometry and HPLC methods under some conditions and found to be in good agreement. To investigate applicability to real samples, the proposed method was applied to the determination of IMD in plum juice.A sensitive square-wave voltammetric method for the determination of lmidacloprid （IMD） was developed using electrochemically pretreated boron-doped diamond （BDD） electrode. Aqueous solutions were prepared with Confidor 200 SL as the commercial formulation of IMD. Sodium sulfate （Na2SO4） was used as supporting electrolyte. The influence of operating parameters, such as the pH of the medium, frequency, pulse amplitude, scan increment and the concentration of IMD was investigated. An irreversible cathodic peak, corresponding to the reduction oflMD is observed at 1.21 V （vs. SCE） and the electrode reaction was controlled by adsorption. Under optimized conditions, the square-wave reduction peak current was linear over the concentration range of （30-200 μmol L 1） with a detection and quantification limits of 8.60 μmol L 1 and 28.67 μmol L 1, respectively. The results were compared with spectrophotometry and HPLC methods under some conditions and found to be in good agreement. To investigate applicability to real samples, the proposed method was applied to the determination of IMD in plum juice.

关 键 词：Imidacloprid Square-wave volammetry Boron-doped diamond electrode Electrochemical detection 

分 类 号：O657.1[理学—分析化学]