碘化铅作为空穴传输层在P3HT：PC(61)BM聚合物太阳能电池中的增强效果  

Lead Iodide as a New Type of Hole Transport Layer for the High Performance of P3HT:PC_(61)BM-Based Solar Cells

作　　者：胥国成 邓先云 李军丽[2] 张睿[3] 谢云鹏[1] 屠国力[2] 夏江滨[3] 卢兴[1] 

机构地区：[1]华中科技大学材料科学与工程学院,材料成型与模具国家重点实验室,武汉430074 [2]武汉光电国家实验室,武汉430074 [3]武汉大学化学与分子科学学院,武汉430072

出　　处：《物理化学学报》2016年第6期1307-1313,共7页Acta Physico-Chimica Sinica

基　　金：国家自然科学基金(51472095)资助项目~~

摘　　要：开发了一类新型阳极界面缓冲材料PbI_2,制备了结构为ITO/PbI_2/P3HT:PC_(61)BM/Al(氧化铟锡导电玻璃/碘化铅/聚三已基噻吩:富勒烯衍生物/铝)的器件,制备工艺包括旋涂和蒸镀,考察了PbI_2在聚合物太阳能电池原型器件ITO/P3HT:PC_(61)BM/Al中的效果。不同碘化铅浓度,退火温度,退火时间,对PbI_2薄膜的质量都会有影响。很显然,高质量的PbI_2薄膜将会带来好的光电转化效率。PbI_2薄膜的透光性,结晶性,以及表面形貌可以用来描述所成薄膜的质量好坏。对能带来最好性能的碘化铅薄膜进行了紫外-可见光谱,X射线粉末衍射(XRD),原子力显微镜(AFM),扫描电子显微镜(SEM)等表征。实验发现,太阳能电池器件的效率对PbI_2浓度比较敏感,最优化的条件为,旋涂浓度为3 mg?m L^(-1),100°C退火30 min,其电池的开路电压(Voc)达到0.45 V,短路电流密度(Jsc)为7.9 m A?cm^(-2),填充因子(FF)为0.46,与没有界面缓冲材料的器件相比,光电转换效率(PCE)由0.85%提高到1.64%。We develop a novel hole extracting buffer layer material,namely PbI_2.The structure of the device we fabricate is ITO/PbI_2/P3HT：PC_（61）BM/Al（indium tin oxide/lead iodide/poly（3-hexylthiophene）：[6,6]-phenyl C61-butyric acid methyl ester/aluminum cathode）.The preparation method involves spin-coating and thermal evaporation.We study the effectiveness of using PbI_2 in the prototype ITO/P3HT：PC_（61）BM/Al polymer solar cell devices.The concentration,annealing temperature,and annealing time all have an influence on the quality of the PbI_2 films.Obviously,higher-quality PbI_2 films will lead to better power conversion efficiency.The transmittance,crystallization,and morphology properties of the PbI_2 films can be used to describe the quality of the films.We characterize the PbI_2 film affording the best performance by UV-Vis spectrophotometry,X-ray powder diffraction（XRD）,atomic force microscopy（AFM）,and scanning electron microscopy（SEM）.Our results reveal that the performance of the solar cell device is sensitive to the concentration of PbI_2,and the best conditions are a concentration of 3 mg？m L^（-1）,annealing temperature of 100 °C,and annealing time of 30 min.The open circuit voltage（Voc） is 0.45 V,the short circuit current density（Jsc） is 7.9 m A？cm^（-2）,and the fill factor（FF） is 0.46.Compared with the devices without any buffer layer（0.85%）,the power conversion efficiency（PCE）using PbI_2 as the buffer layer can reach 1.64%.

关 键 词：聚合物太阳能电池 阳极界面缓冲层 碘化铅 浓度 光电转化效率 

分 类 号：TM914.4[电气工程—电力电子与电力传动]