酚醛树脂制备活性炭的工艺  

Craft Research of Preparing Activated Carbon by Phenolic Resin

作　　者：刘肖强 李奕怀[1] 张素娜[1] 燕溪溪 汪玲玲[1] 吴敏昌[2] 朱路平[1] 邴乃慈[1] 乔永民[2] 王利军[1] 

机构地区：[1]上海第二工业大学环境与材料工程学院,上海201209 [2]上海杉杉科技有限公司,上海201209

出　　处：《上海第二工业大学学报》2016年第2期107-111,共5页Journal of Shanghai Polytechnic University

基　　金：国家自然科学基金(No.51174274;No.21101105);上海市曙光计划(No.09SG54);上海市教育委员会科研创新项目(No.12ZZ195);浦东新区科技发展基金创新资金(No.PKJ2014-Z03)资助

摘　　要：以酚醛树脂为原料、氢氧化钾为活化剂,经过一系列的单因素实验,分别考察了活化温度、碱脂比及活化时间对碘吸附值和活性炭收率的影响。结果表明:当活化温度为800?C、碱脂比为2:1、活化时间为90 min时,制备的活性炭样品的碘吸附值和活性炭收率分别为1 531.72 mg/g和73.90%。采用热重-差热分析仪(TG-DTA)、电子显微镜(SEM)、傅里叶红外光谱仪(FTIR)、X射线衍射仪(XRD)等仪器,分别对活性炭样品的炭化活化过程、表面形态、表面官能团、物相结构进行了表征。To phenolic resin as raw material, using KOH as the activating agent. It was investigated the effects of activation temperature,the ratio of KOH to phenolic resin and activation time on iodine number and yield of activated carbon after a series of single-factorexperiments. The results showed that when the activation temperature at 800 ±C, the ratio of KOH to phenlic resin was 2 ： 1, activationtime for 90 min, activated carbon has iodine adsorption of 1 531.72 mg/g and yield of 73.90%. The progress of carbonization andactivation surface morphology, surface functional group, phase structure were characterized by Thermogravimetry-Differential ThermalAnalysis （TG-DTA）, Scanning Electron Microscope （SEM）, Fourier Transform Infrared Spectroscopy （FTIR） and X-Ray Diffraction（XRD）.

关 键 词：酚醛树脂 活性炭 制备 碘吸附值 

分 类 号：TQ424.1[化学工程]