HfB_2-HfC-SiC改性C/C复合材料的超高温烧蚀性能研究  

Ablation Behaviors of HfB_2-HfC-SiC Ceramic Modified C/C Composites at Ultra-high Temperature

作　　者：魏玺[1] 李捷文[1] 张伟刚[1] 

机构地区：[1]中国科学院过程工程研究所多相复杂系统国家重点实验室,北京100190

出　　处：《装备环境工程》2016年第3期12-17,共6页Equipment Environmental Engineering

基　　金：国家自然科学基金(51272251;51402300)~~

摘　　要：目的制备HfB_2-HfC-SiC复相陶瓷改性C/C复合材料,并探究该材料的超高温烧蚀性能。方法采用化学气相渗透结合前驱体浸渍热解工艺制备HfC-SiC复相陶瓷改性C/C复合材料(C/C-HfC-SiC)和HfB_2-HfC-SiC复相陶瓷改性C/C复合材料(C/C-HfB_2-HfC-SiC),采用大气等离子烧蚀实验研究材料的超高温烧蚀性能。结果C/C-HfC-SiC和C/C-HfB_2-HfC-SiC复合材料2200℃线烧蚀率分别为1.54×10^(-3),1.38×10^(-3)mm/s。结论复合材料具有独特的微结构特征,亚微米级的HfB_2和HfC基体均匀弥散分布在SiC基体中。复合材料表面原位生成的液相SiO_2和固相HfO_2复合氧化物膜,既可以抵抗高速气流的冲蚀,又可以抵抗氧化性气氛的向内扩散,是复合材料具有优异超高温抗烧蚀性能的主要原因。Objective To fabricate HfB2-Hf C-Si C ceramic modified C/C composites and investigate the ablation performance of the composites at ultra-high temperature. Methods Chemical vapor infiltration（CVI） combined with precursor impregnation pyrolysis（PIP） method were used to fabricate Hf C-SiC ceramic modified C/C composites（C/C-Hf C-SiC） and HfB2-Hf C-SiC ceramic modified C/C composites（C/C-HfB2-Hf C-SiC）. Atmospheric plasma torch was used to investigate the ablation performance of the composites. Results Linear ablation rates of C/C-Hf C-SiC and C/C-HfB2-Hf C-SiC composites at 2200 ℃ were 1.54×10^-3 mm/s and 1.38×10^-3 mm/s respectively. Conclusion The composites had unique microstructural features, with nano-sized HfB2 and Hf C particles uniformly distributed in Si C phase. The liquid-phase SiO2 and the solid-phase HfO2 composite oxides film in situ formed on the surface of the composites could resist not only the erosion of high-speed gas flow, but also the inward diffusion of oxidative gases, which was the main cause for the excellent ablation resistance of the composites at ultra-high temperature.

关 键 词：C/C复合材料 基体改性 HfB2 HFC 烧蚀性能 

分 类 号：TJ04[兵器科学与技术—兵器发射理论与技术] TB321[一般工业技术—材料科学与工程]