Microwave-assisted One-pot Synthesis of Ag NPs/C and Its Application in H2O2 and Glucose Detection  

作　　者：GE Chenjiao LU Wenbo SUN Xuping TIAN Jian 

机构地区：[1]Clean Energy lechnology Laboratory, Changchun University of Science and Technology, Changchun 130022, P. R. China [2]State Key Lab of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P R. China

出　　处：《Chemical Research in Chinese Universities》2016年第3期433-436,共4页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China（No.21175129）, the National Basic Research Program of China（No.2011CB935800） and the Scientific and Technological Development Plan Project of Jilin Province, China（No. 20100534）.

摘　　要：The facile preparation of Ag NPs/C via a one-pot strategy was carried out by microwave treatment of a mixed aqueous solution of AgNO3 and glucose at 180 ℃ for 20 min without the presence of extra reducing agent. The as-synthesized Ag NPs/C showed high catalytic performance toward the reduction of H2O2. The H2O2 sensor constructed with as-synthesized Ag NPs/C exhibited a short amperometric response time of less than 2 s. The linear range was approximately （0.1-50） mmol/L（r=0.997）, and the detection limit was approximately 3.3 μmol/L at a signal-to-noise ratio of 3. A glucose biosensor was fabricated by immobilizing glucose oxidase onto Ag NPs/C- modified glassy carbon electrode to detect glucose. The glucose sensor had a wide linear response range of 2-22 mmol/L（r=0.999） and a detection limit of 190 μmol/L.The facile preparation of Ag NPs/C via a one-pot strategy was carried out by microwave treatment of a mixed aqueous solution of AgNO3 and glucose at 180 ℃ for 20 min without the presence of extra reducing agent. The as-synthesized Ag NPs/C showed high catalytic performance toward the reduction of H2O2. The H2O2 sensor constructed with as-synthesized Ag NPs/C exhibited a short amperometric response time of less than 2 s. The linear range was approximately （0.1-50） mmol/L（r=0.997）, and the detection limit was approximately 3.3 μmol/L at a signal-to-noise ratio of 3. A glucose biosensor was fabricated by immobilizing glucose oxidase onto Ag NPs/C- modified glassy carbon electrode to detect glucose. The glucose sensor had a wide linear response range of 2-22 mmol/L（r=0.999） and a detection limit of 190 μmol/L.

关 键 词：Carbon Ag nanoparticles Microwave H2O2 GLUCOSE 

分 类 号：TQ225.241[化学工程—有机化工] Q554[生物学—生物化学]