活性开环移位聚合在制备功能大分子中的应用  

Application of Ring-Opening Metathesis Polymerization in Synthesis of Functional Macromolecules

作　　者：李凯[1] 徐梵[1] 冯露[1] 张延武[1] 

机构地区：[1]郑州大学化工与能源学院,河南郑州450001

出　　处：《化学反应工程与工艺》2015年第6期515-521,529,共8页Chemical Reaction Engineering and Technology

基　　金：国家自然科学基金(50903074)

摘　　要：首先介绍了活性开环移位聚合的机理、特点和Grubbs催化剂的发展,然后综述了近年来活性开环移位聚合在功能均聚物及共聚物合成中的应用,以及使用该方法合成的功能聚合物在材料、能源、生物和医疗等领域的应用,最后指出了开环移位聚合所面临的主要挑战。Firstly the mechanism of ring-opening metathesis polymerization（ROMP） and the development of Grubbs catalyst were introduced in this review.Then,the application of ROMP in synthesis of functional homopolymers and copolymers,and the application of these copolymers in the area of material,energy,biology and medical treatment were reviewed.Finally,the challenge of ROMP in future was pointed out.

关 键 词：活性聚合 开环移位聚合 功能大分子 降冰片烯 

分 类 号：O643.32[理学—物理化学] TQ316.3[理学—化学]