二氯化一氯·五氨合钴(Ⅲ)制备实验条件探究与优化  

Exploration and Improvement of Experimental Condition on Preparation for Chloro-Pentammine-Cobaltichloride

作　　者：赵鑫[1] 蒋军泽 王雅岚[1] 刘建萍 胡小莉[1] 李原芳[1] 

机构地区：[1]西南大学化学化工学院,重庆400715 [2]重庆第48中学,重庆400700

出　　处：《西南师范大学学报（自然科学版）》2016年第7期181-184,共4页Journal of Southwest China Normal University(Natural Science Edition)

摘　　要：本科"无机制备"课程中"二氯化一氯·五氨合钴(Ⅲ)的制备"实验需使用大量有毒试剂——浓氨水和浓盐酸,且二者相遇将产生污染严重的刺激性白色烟雾——氯化铵颗粒,给实验室及周边环境造成极大污染,严重影响广大师生的身体健康.针对这些问题,对制备反应的条件进行了探究和优化,成功地用稀盐酸、稀氨水代替了浓盐酸、浓氨水,为今后开设该实验提供了一套科学合理、操作简便、绿色环保的实验方案.This article is aimed at the experim ent^ problem of the Preparation of [C o （N H 3 ） 5 C1]C12 for collegeundergraduate, heavily polluted w hite sm oke particles-am m onium chloride are produced because alarge num ber of toxic reagent concentrated am m onia and concentrated hydrochloric acid w ere used. Laboratoryand the surrounding environm ent has been polluted, the health of teachers and students are affected.In view of the above problem s, all the influential factors w ere studied by the m ono-factor experim ents.D ilute hydrochloric acid, dilute am m onia w ater is used to replace the concentrated hydrochloric acid, concentratedam m onia, w hich provided the course Inorganic P reparation w ith a scientific and reasonable, easyto operate, green environm ental protection scheme .

关 键 词：二氯化一氯·五氨合钴(Ⅲ) 制备 实验优化 

分 类 号：O614.81[理学—无机化学] O631[理学—化学]