Simultaneously Improving the Tensile and Impact Properties of Isotactic Polypropylene with the Cooperation of co-PP and β-nucleating Agent through Pressure Vibration Injection Molding  

作　　者：Man Zhou Xin-peng Li Ming Jin Chao Xia Kai-zhi Shen 张杰 

机构地区：[1]College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China

出　　处：《Chinese Journal of Polymer Science》2016年第8期1001-1013,共13页高分子科学（英文版）

摘　　要：In this article, crystalline morphology and molecular orientation of isotactic polypropylene （iPP）, random copolymerized polypropylene （co-PP） and ,β-nucleating agent （β-NA） composites prepared by pressure vibration injection molding （PVIM） have been investigated via polarized light microscopy, scanning electron microscopy, wide-angle X-ray diffraction and differential scanning calorimetry. Results demonstrated that the interaction between co-PP and iPP molecular chains was beneficial for the mechanical improvement and the introduction of β-NA further improved the toughness of iPP. In addition, after applying the pressure vibration injection molding （PVIM） technology, the shear layer thickness increased remarkably and the tensile strength improved consequently. Thus, the strength and toughness of iPP/co-PP/β-NA composites prepared by PVIM were simultaneously improved compared to those of the pure iPP prepared by conventional injection molding （CIM）： the impact toughness was increased by five times and tensile strength was increased by 9 MPa. This work provided a new method to further enhance the properties of iPP/co-PP composites through dynamic processing strategy.In this article, crystalline morphology and molecular orientation of isotactic polypropylene （iPP）, random copolymerized polypropylene （co-PP） and ,β-nucleating agent （β-NA） composites prepared by pressure vibration injection molding （PVIM） have been investigated via polarized light microscopy, scanning electron microscopy, wide-angle X-ray diffraction and differential scanning calorimetry. Results demonstrated that the interaction between co-PP and iPP molecular chains was beneficial for the mechanical improvement and the introduction of β-NA further improved the toughness of iPP. In addition, after applying the pressure vibration injection molding （PVIM） technology, the shear layer thickness increased remarkably and the tensile strength improved consequently. Thus, the strength and toughness of iPP/co-PP/β-NA composites prepared by PVIM were simultaneously improved compared to those of the pure iPP prepared by conventional injection molding （CIM）： the impact toughness was increased by five times and tensile strength was increased by 9 MPa. This work provided a new method to further enhance the properties of iPP/co-PP composites through dynamic processing strategy.

关 键 词：Mechanical properties Orientation structures Periodical shear field Morphology. 

分 类 号：TQ325.14[化学工程—合成树脂塑料工业]