铁酸盐-还原石墨烯复合材料的制备及其对亚甲基蓝的吸附  

Preparation of magnetic reduced graphene oxide-ferrite hybrids and its adsorption of methylene blue

作　　者：王骥[1,2] 贾宝平[1,2] 袁宁一[1,2] 丁建宁[1,2] 

机构地区：[1]常州大学光伏科学与工程协同创新中心,常州213164 [2]常州大学材料科学与工程学院,常州213164

出　　处：《环境工程学报》2016年第7期3616-3622,共7页Chinese Journal of Environmental Engineering

基　　金：国家自然科学基金资助项目(21301021)

摘　　要：以氯化铁(FeCl_3·6H_2O)、氯化锰(MnCl_2·4H_2O)、氯化锌(ZnCl_2)、氯化钴(CoCl_2·6H_2O)、氯化镍(NiCl_2·6H_2O)和氧化石墨烯(GO)为原料,制备了4种铁酸盐与还原氧化石墨烯(RGO)的复合材料(RGO-MFe_2O_4,M=Mn,Zn,Co或Ni),通过扫描电子显微镜、X-射线衍射仪、拉曼光谱仪进行了表征,系统研究了4种材料对亚甲基蓝的吸附。结果发现,RGO-NiFe_2O_4对亚甲基蓝的吸附能力最好,而对吸附起主要作用的是RGO。随着温度升高、染料初始浓度的增加和吸附时间的延长,RGO-NiFe_2O_4吸附量逐渐增大。RGO-NiFe_2O_4对亚甲基蓝的吸附动力学拟合符合伪二级动力学模型。吸附等温线模型拟合结果表明,Langmuir方程可以很好地描述其对亚甲基蓝的吸附。热力学参数ΔG^0在不同温度下均为负值,ΔH^0为正值,ΔS^0为正值说明吸附过程是自发的吸热反应。Magnetic reduced graphene oxide-ferrite hybrids（ RGO-MFe_2O_4,where M = Mn,Zn,Co,or Ni）were prepared from FeCl_3·6H_2O,MnCl_2·4H_2O,ZnCl_2,CoCl_2·6H_2O,NiCl-2·6H_2O,and graphene oxide（ GO）. The hybrids were characterized using scanning electron microscopy（ SEM）,X-ray diffraction（ XRD）,and Raman spectroscopy,and their methylene blue adsorption was systematically studied. RGO played a major role in the adsorption of methylene blue,and results indicated that RGO-NiFe_2O_4 had the highest adsorption capacity. A greater degree of adsorption was observed with increasing temperature as the initial concentration of methylene blue rose over time. The adsorption kinetics followed a pseudo-second-order kinetic equation,and a methylene blue adsorption isotherm was fitted using a Langmuir model. The adsorption process was determined to be spontaneous and exothermic,owing to thermodynamic parameters of negative ΔG^0 and positive ΔH^0 and ΔS^0.

关 键 词：铁酸盐 石墨烯 亚甲基蓝 吸附动力学 吸附等温线 热力学参数 

分 类 号：X703[环境科学与工程—环境工程]