Synthesis of biomimetic cerium oxide by bean sprouts bio-template and its photocatalytic performance  

作　　者：周梦凯 张凯 陈丰 陈志刚 

机构地区：[1]School of Material Science and Engineering,Jiangsu University [2]School of Chemistry,Biology and Materials Engineering,Suzhou University of Science and Technology

出　　处：《Journal of Rare Earths》2016年第7期683-688,共6页稀土学报（英文版）

基　　金：Project supported by the National Natural Science Foundation of China(21277094,51478285,21407111);Natural Science Foundation of Jiangsu Province(BK2012167,BK20140280);Collegiate Natural Science Fund of Jiangsu Province(14KJA430004,12KJA430005);the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD);Applied Basic Research Project of Suzhou(SYG201316);Jiangsu Key Laboratory for Environment Functional Materials(SJHG1304,SJHG1310);Creative Project of Postgraduate of Jiangsu Province(CXZZ13_0855);Excellent Innovation Team in Science and Technology of University in Jiangsu Province and Collabrative Innovation Center of Technology and Material of Water Treatment

摘　　要：Biomimetic nano CeO2 materials were prepared by using bean sprouts as bio-template through impregnation and thermal decomposition. For characterization of structure, X-ray diffraction spectroscopy （XRD）, field emission scanning electron microscopy （FESEM）, transmission electron microscopy （TEM）, UV-Vis diffuse reflectance spectra （UV-Vis/DRS） nitrogen adsorp- tion-desorption measurements and Labsolar H2 system were adopted. The results demonstrated that the samples prepared at 550 ℃ not only completely removed the original bio-template, but also retained the morphology and microstructure of bean sprouts. Then the biomorphic structure of fluorite structure CeO2 material was obtained. Micro-pores with a diameter of about 2-3 nm were distributed among the particles, which provided more favorable channel for the photocatalytic reaction. Biomimetic CeO2 materials exhibited clear red shift （50 nm） compared with powder CeO2, which could be excited by visible irradiation. Biomimetic CeO2 materials dis- played the superior photocatalytic activity for the hydrogen production by water splitting under the sunlight irradiation, the hydrogen yield could reach 400 ktmol/g catalyst after 6 h.Biomimetic nano CeO2 materials were prepared by using bean sprouts as bio-template through impregnation and thermal decomposition. For characterization of structure, X-ray diffraction spectroscopy （XRD）, field emission scanning electron microscopy （FESEM）, transmission electron microscopy （TEM）, UV-Vis diffuse reflectance spectra （UV-Vis/DRS） nitrogen adsorp- tion-desorption measurements and Labsolar H2 system were adopted. The results demonstrated that the samples prepared at 550 ℃ not only completely removed the original bio-template, but also retained the morphology and microstructure of bean sprouts. Then the biomorphic structure of fluorite structure CeO2 material was obtained. Micro-pores with a diameter of about 2-3 nm were distributed among the particles, which provided more favorable channel for the photocatalytic reaction. Biomimetic CeO2 materials exhibited clear red shift （50 nm） compared with powder CeO2, which could be excited by visible irradiation. Biomimetic CeO2 materials dis- played the superior photocatalytic activity for the hydrogen production by water splitting under the sunlight irradiation, the hydrogen yield could reach 400 ktmol/g catalyst after 6 h.

关 键 词：bio-template nano materials PHOTOCATALYSIS hydrogen production rare earths 

分 类 号：O614.332[理学—无机化学] TB383.1[理学—化学]