1945年银行票据样品印刷颜料无损鉴定  

Non-Destructive Identification of Pigments Printed on the Bank Bill Issued in 1945

作　　者：季金鑫 周文华[1] 姚娜[1] 甘清[1] 王纪刚[1] 周忠[1,2] 施继龙[1] 

机构地区：[1]北京印刷学院印刷与包装工程学院,北京102600 [2]北京印刷学院北京绿色印刷包装产业技术研究院,北京102600

出　　处：《光谱学与光谱分析》2016年第7期2207-2212,共6页Spectroscopy and Spectral Analysis

基　　金：国家科技支撑计划项目(2014BAH07F01);北京市科技新星计划项目(2010B034);文件检验鉴定公安部重点实验室开放课题(2015)资助

摘　　要：利用超景深三维视频显微镜、激光显微共聚焦拉曼光谱仪、扫描电镜-能谱仪等,对一张1945年银行票据样品的印刷颜料进行测试分析,结果显示该票据印刷使用了颜料红146和颜料红53:1等有机颜料,以及朱砂、碳黑、普鲁士蓝、副雄黄和x构型雄黄等无机颜料,并推测棕黑色手写字迹由蓝黑墨水老化褪色形成。票据中各处色块多为单一呈色,有两处印章由朱砂与不同晶型的雄黄共同呈色,并且首次发现x构型雄黄和副雄黄作为印刷颜料使用。研究表明,上述三项技术的联用可以成功地对纸质品上的有机及无机颜料进行无损鉴定,在纸质文物研究中具有广阔的应用前景。Three-dimensional video microscopy ,Raman spectrometer and scanning electron microscopy-energy dispersive spec-troscopy （SEM-EDS） were employed to analyze the pigments of various colors on a sample of bank bill issued in 1945 .The re-sults indicated that organic pigments including C .I .Pigment Red 146 and C .I .Pigment Red 53∶1 ,and inorganic pigments such as cinnabar ,parareaglar ,χ-phase of realgar ,carbon black and Prussian blue were used in printing ;the brown-black hand-writing letters were speculated to be formed from the fading black-blue ink .Most areas of the bank bill were in one single color with one pigment ,but two areas of orange-red seals were checked to be colored with cinnabar and two different phases of real-gar ,and the parareaglar ,and χ-phase of realgar were found to be used as printing pigments firstly .This study shows that com-bining with three technologies above-mentioned is viable and it has great application potential in non-destructive identification of organic and inorganic pigments on paper-based cultural heritage .

关 键 词：票据样品 颜料 无损分析 

分 类 号：J212.6[艺术—美术]