Pt/Y2O3：Eu3＋ composite nanotubes： Enhanced photoluminescence and application in dye-sensitized solar cells  

作　　者：Mingqi Yu Jiamin Su Guofeng Wang Yadong Li 

机构地区：[1]Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China [2]Department of Chemistry, Tsinghua University, Beijing 100084, China

出　　处：《Nano Research》2016年第8期2338-2346,共9页纳米研究（英文版）

基　　金：This work was supported by the National Natural Science Foundation of China （No. 21471050） and Heilongjiang Province Natural Science Foundation of Key Projects （No. ZD201301）.

摘　　要：Y（OH）3：Eu3＋ nanotubes were synthesized using a facile hydrothermal method, and then, Pt particles were grown on the surface of the nanotubes using a combination of vacuum extraction and annealing. The resulting Pt/Y2O3：Eu3＋ composite nanotubes not only exhibited enhanced red luminescence under 255- or 468-nm excitation but could also be used to improve the efficiency of dye- sensitized solar cells, resulting in an efficiency of 8.33%, which represents a significant enhancement of 11.96% compared with a solar cell without the com- posite nanotubes. Electrochemical impedance spectroscopy results indicated that the interfacial resistance of the TiO2-dyel I3/I- electrolyte interface of the TiO2-Pt/Y203：Eu3~ composite cell was much smaller than that of a pure TiO2 cell. In addition, the TiO2-Pt/Y2O3：Eu3＋ composite cell exhibited a shorter electron transport time and longer electron recombination time than the pure TiO2 cell.Y（OH）3：Eu3＋ nanotubes were synthesized using a facile hydrothermal method, and then, Pt particles were grown on the surface of the nanotubes using a combination of vacuum extraction and annealing. The resulting Pt/Y2O3：Eu3＋ composite nanotubes not only exhibited enhanced red luminescence under 255- or 468-nm excitation but could also be used to improve the efficiency of dye- sensitized solar cells, resulting in an efficiency of 8.33%, which represents a significant enhancement of 11.96% compared with a solar cell without the com- posite nanotubes. Electrochemical impedance spectroscopy results indicated that the interfacial resistance of the TiO2-dyel I3/I- electrolyte interface of the TiO2-Pt/Y203：Eu3~ composite cell was much smaller than that of a pure TiO2 cell. In addition, the TiO2-Pt/Y2O3：Eu3＋ composite cell exhibited a shorter electron transport time and longer electron recombination time than the pure TiO2 cell.

关 键 词：Pt/Y2O3：Eu3＋ NANOCRYSTALS LUMINESCENCE dye-sensitized solar cells 

分 类 号：O[理学]