高性能纳米复合薄膜制备及其非线性光学性质研究  

Recent Advances on Preparation and Non-linear Optical Response of High-performance Nanocomposite Films

作　　者：华子乐[1] 顾金楼[1] 崔方明[1] 施剑林[1] 

机构地区：[1]中国科学院上海硅酸盐研究所,上海200050

出　　处：《空间科学学报》2016年第4期438-444,共7页Chinese Journal of Space Science

基　　金：载人航天工程天宫二号综合材料项目资助

摘　　要：介孔薄膜是介孔材料中的一种重要材料形式.根据介孔基纳米复合薄膜制备科学及非线性光学性能研究现状,基于相似相容原理、离子交换、无电沉积、电沉积、沉积-沉淀等新方法设计在介孔薄膜中实现金属与半导体纳米粒子高效及高分散性组装的系列结果,重点分析了合成纳米复合薄膜材料的非线性光学性质,研究了外场环境,特别是强磁场条件下的热处理过程对纳米金负载介孔基纳米复合薄膜结构与非线性光学性质的影响.Researches on mesoporous materials have got great progress in the past decade.Recent advances of our group on the study of preparation and non-linear optical response of highperformance mesoporous-based nanocomposite films are summarized.Special attentions are focused on new methodology design for the highly efficient and homogeneous incorporation of the metal or semiconductor nanoparticles in the pore channels of mesoporous thin films.These new methodologies include like-dissolves-like,ion-exchange,electroless deposition,electric deposition,depositionprecipitation and surface-modification protocols with mesoporous silica or titania matrix.Afterwards,the non-linear optical responses of the resultant nanocomposite films and the thermally post-treated ones in the presence or absence of magnetic field are analyzed.Finally,some perspectives for the further development of mesoporous nanocomposites films are also discussed.

关 键 词：纳米材料 介孔材料 非线性光学 

分 类 号：TB383.1[一般工业技术—材料科学与工程]