金属有机骨架材料(MOFs)的合成及应用研究  

Study on Synthesis Methods and Applications of Metal-organic Frameworks Material( MOFs)

作　　者：李莹[1,2] 张红星[1,2] 闫柯乐[1,2] 孙晓英[1,2] 杨静怡[1,2] 邹兵[1,2] 

机构地区：[1]中石化青岛安全工程研究院,山东青岛266071 [2]化学品安全控制国家重点实验室,山东青岛266071

出　　处：《广州化工》2016年第15期24-27,共4页GuangZhou Chemical Industry

摘　　要：金属有机骨架材料(MOFs)是由有机配体与金属离子自组装形成的一种新型的具有周期性的多孔骨架材料。首先讨论了MOFs材料的不同合成方法 (缓慢扩散法、水热法、一锅法、电化学、机械化学法、微波辅助加热法和超声法等);其次总结了多功能MOFs材料的应用(氢气和甲烷的储存、CO_2捕获、有毒化合物的选择性吸附、多相催化和金属缓蚀等);最后展望了MOFs材料的工业应用前景。Metal-organic frameworks material （MOFs） is a new kind of porous skeleton material by self-assembly with organic ligands and metal ions. Different synthetic methods of MOFs, such as slow diffusion, hydro （solvo） thermal, one-pot, electrochemical, meehanochemical, microwave-assisted heating and ultrasonic, were discussed The applications of multi-functional MOFs materials were summarized, such as hydrogen and methane storage, CO2 capture, removal of harmful and toxic chemicals, heterogeneous catalysis, luminescence and metal corrosion inhibition. Industrial application prospect of MOFs materials was prospected.

关 键 词：金属有机骨架材料 合成方法 多功能 应用前景 

分 类 号：O61[理学—无机化学]