草酸葑醇酯的合成及其表征  

Synthesis and Characterization of Fenchyl Oxalate

作　　者：袁晓敏[1] 赵振东[1,2] 徐士超[1,2] 卢言菊[1,2] 朱守记[1] 

机构地区：[1]中国林业科学研究院林产化学工业研究所,生物质化学利用国家工程实验室,国家林业局林产化学工程重点开放性实验室,江苏省生物质能源与材料重点实验室,江苏南京210042 [2]中国林业科学研究院林业新技术研究所,北京100091

出　　处：《生物质化学工程》2016年第4期1-5,共5页Biomass Chemical Engineering

基　　金：农业科学技术成果转化资金项目(2013GB24320604)

摘　　要：以α-葑醇和草酰氯为原料合成草酸葑醇酯,考察了反应条件对葑醇酯化反应的影响,确定了葑醇酯化反应的较佳条件:草酰氯与葑醇的物质的量之比为0.6∶1.0,反应温度为55℃,反应时间10 h,最佳条件下目标产物收率为93.9%,重结晶后纯度可达99.9%。采用GC-MS、IR、1H NMR、13C NMR等对合成的草酸葑醇酯进行了结构表征。Fenchyl oxalate was synthesized by the reaction of α-fenchyl alcohol and oxalyl chloride. The influences of reaction conditions on the esterification were studied. The optimum conditions of the esterification were the molar ratio of oxalyl chloride and fenchyl alcohol 0.6：1.0,reaction temperature 55℃ and reaction time lOh.Under these conditions, the yield of fenchyl oxalate was 93.9 %.After recrystallization,the purity could be 99.9 %.And the structure of fenchyl oxalate was characterized by GC-MS, IR, 1H NMR and 13C NMR.

关 键 词：葑醇 草酰氯 草酸葑醇酯 表征 

分 类 号：TQ223.27[化学工程—有机化工]