双(1,2,4-二唑膦)甲烷铜配合物的制备及磁性研究  

Preparation and Magnetic Research on Bis(1,2,4-diazaphospholyl) methane Copper Complexs

作　　者：刘晓玲[1,2] 范莉莉[2] 赵明刚[1] 

机构地区：[1]山西师范大学,山西临汾041004 [2]银川能源学院,宁夏银川750105

出　　处：《皮革与化工》2016年第4期26-30,共5页Leather And Chemicals

基　　金：银川能源学院科研基金项目;项目编号2015-KY-Y-45

摘　　要：将合成的双(3,5-二取代基)吡唑膦甲烷[H(L1)]作为原料,与铜的化合物在甲醇做溶剂的条件下,按照一定的比例反应,得到新的铜配合物。得到的新物质用核磁共振、X-Ray单晶衍射等分析方法进行结构表征以后,主要研究其在磁性方面的性质。该材料作为一种新型的催化剂材料,主要可在医药、纺织、涂料、金属缓蚀、皮革等方面做大量的应用。Bis（1,2,4-diazaphospholyl） methane （L1） was used to react with CuC12, Cu（C104）2 in methanol respectively. According to the definite proportion, the new copper complex was obtained . The complexes were characterized by NMR spectrum and X-Ray single cryst-al diffraction, especially in magnetic property. The two complexes could be used as magnetic materials. As a new kind of catalyst material, this material can be applied mainly in pharmaceutical, textile, paint, metal corrosion and leather.

关 键 词：1 2 4-二唑膦 分子磁性材料 铜配合物 

分 类 号：O641.4[理学—物理化学]