新型可溶性酞菁锌的微波合成和光谱性质  

Microwave-induced synthesis and spectral property of novel soluble Zinc phthalocyanine

作　　者：白青龙[1] 赵宏蕊 张春花[1] 宋娟娟[1] 

机构地区：[1]内蒙古民族大学化学化工学院,通辽028043

出　　处：《化工新型材料》2016年第8期151-152,共2页New Chemical Materials

基　　金：内蒙古民族大学博士科研启动基金(BS289;BS314);内蒙古民族大学科学研究基金资助项目(NMDYB15076)

摘　　要：以3-(4-甲基-2-叔丁基苯氧基)邻苯二腈和乙酸锌为原料,通过微波辐射法合成了1,8,15,22-四-(4-甲基-2-叔丁基苯氧基)酞菁锌,通过红外光谱、紫外-可见光谱和质谱表征了其结构,并研究了取代基结构对其吸收光谱和荧光光谱的影响。1,8,15,22-tetra-（4-methyl-2-tert-butyl phenoxy） phthalocyanine zinc was synthesized used microwave radiation. The major precursors were 3-（4-methyl-2-tert butyl phenoxy）-1, 2-dicarbonitrile in raw materials. The products were characterized by IR spectra, UV-Vis spectra and MS spectra, respectively. And the influence of substituent group structure to UV- Vis and fluorescence spectra properties of products were studied.

关 键 词：酞菁 微波合成 紫外-可见光谱 荧光光谱 

分 类 号：O627.23[理学—有机化学]