Corrosion Mechanism of E-glass of Chemical Resistance Glass Fiber in Acid Environment  

作　　者：谢俊 YIN Peng SHI Weiguang HU Min 王静 ZHOU Xuedong HAN Jianjun CAO Shaowen HAN Lixiong YAO Yuan 

机构地区：[1]State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China [2]Chongqing Polycomp International Corp., Chongqing 400082, China

出　　处：《Journal of Wuhan University of Technology(Materials Science)》2016年第4期872-876,共5页武汉理工大学学报（材料科学英文版）

基　　金：Funded by the National Natural Science Foundation of China(No.51472191);the Wuhan City Chenguang Project(No.2014070404010208);the Natural Science Foundation of Hubei Province(Nos.2014CFB343 and 2014CFB859);the Doctoral Program of Higher Education(No.20130143110013);the Key Technology Innovation Project of Hubei Province(No.2013AAA017)

摘　　要：The corrosion of ECR glass fiber was investigated by the analysis methods of weight loss ratio under different acids and at various durations.Weight loss,leaching of cations,and surface composition of ECR glass fiber were analyzed.The corrosion mechanism of ECR glass fiber in acid environment was also discussed.The experimental results showed that the corrosion degree of ECR glass fiber in different acids obeyed the order： HNO3〉H2SO4〉HCl.The acid effects on corrosion of ECR glass fiberis were totally different.Hydrochloric acid mainly destroyed the network structure of [AlO4],while sulfuric acid and nitric acid mainly destroyed the structure of [SiO4].The acid resistance of ECR glass fiber is much better than that of E glass fiber due to the generation of intermediate product silicic acid gel Si（OH）4 during ion exchange.It can adhere to the glass surface to form a thin film and hinder the proceeding of corrosion.The corrosion of ECR glass fiber was investigated by the analysis methods of weight loss ratio under different acids and at various durations.Weight loss,leaching of cations,and surface composition of ECR glass fiber were analyzed.The corrosion mechanism of ECR glass fiber in acid environment was also discussed.The experimental results showed that the corrosion degree of ECR glass fiber in different acids obeyed the order： HNO3〉H2SO4〉HCl.The acid effects on corrosion of ECR glass fiberis were totally different.Hydrochloric acid mainly destroyed the network structure of [AlO4],while sulfuric acid and nitric acid mainly destroyed the structure of [SiO4].The acid resistance of ECR glass fiber is much better than that of E glass fiber due to the generation of intermediate product silicic acid gel Si（OH）4 during ion exchange.It can adhere to the glass surface to form a thin film and hinder the proceeding of corrosion.

关 键 词：hinder destroyed sizing adhere totally boron melting reaches leaching inorganic 

分 类 号：TQ171.771[化学工程—玻璃工业]