不同价态Mn(Ⅱ,Ⅲ,Ⅴ)催化的烯烃环氧化反应研究进展  

Research Progress on Epoxidation of Olefins Catalyzed by Mn(Ⅱ,Ⅲ,Ⅴ) in Different Valence States

作　　者：邹晓川[1,2] 石开云[1] 李俊[1] 王跃[1] 王存[1] 邓朝芳[1] 任彦荣[1] 谭君[1] 傅相锴[2] 

机构地区：[1]重庆第二师范学院生物与化学工程系,南岸400067 [2]西南大学化学化工学院应用化学研究所,重庆市应用化学重点实验室,三峡库区生态环境教育部重点实验室,北碚400715

出　　处：《有机化学》2016年第8期1765-1778,共14页Chinese Journal of Organic Chemistry

基　　金：重庆市基础与前沿研究(Nos.cstc2015jcyj A0317,cstc2013jcyj A50033);重庆市教育委员会科学技术研究(Nos.KJ1501411,KJ131513,KJ131512);重庆市高校创新团队研究(No.KJTD201325);重庆第二师范学院绿色合成与分析检测重点实验室(No.16xjpt08);重庆第二师范学院创新团队(No.KYC-cxtd03-20141z02)资助项目~~

摘　　要：在过去的十多年中,由过渡金属(Cr,Ni,Co,Ru,Mn)参与催化的烯烃环氧化反应受到人们的大量关注,制备的环氧化物中间体被广泛应用于医药、农药以及精细化学品的合成.相比其它过渡金属,Mn及其配合物催化剂具有廉价、环境友好、化学稳定性高、催化效率高等优点.综述了不同氧化价态的Mn(Ⅱ,Ⅲ,Ⅴ)与不同NXOY配体形成的催化剂,在不同的氧化剂/助催化剂参与下高效催化烯烃环氧化反应的研究现状,同时,对不同价态的Mn催化剂参与烯烃环氧化过程以及活性氧中间体如何将氧转移给烯烃的机理进行讨论.The epoxidation catalyzed by transition metals （Cr, Ni, Co, Ru, Mn） has been received widespread attention over the past decades, and the corresponding epoxides are widely used in the synthesis of pharmaceuticals, fine chemicals and pesticides. Compared to other transition metals, metal Mn catalyst has been widely used in organic synthesis due to its inexpensive, environment-friendly, chemical stability and high catalytic activity. This paper reviews the recent progress on epoxidation of olefins catalyzed by the catalysts which were formed by the reaction of different valence metal Mn（II, III, and V） and dif- ferent NxOy ligands in different oxidants/co-catalyst systems. At the same time, the Mn catalysts with different valence states are involved in the process of the epoxidation of olefins and the mechanism of how to transfer the oxygen of reactive intermediates to the olefins was discussed.

关 键 词：金属锰(II III V)催化剂 配体 环氧化 有机聚合物/无机磷酸盐(Zr Zn Al Ca) 催化机理 

分 类 号：O643.36[理学—物理化学]