芳香杂环硫醚类化合物的合成研究  

Synthesis of Aromatic Heterocyclic Sulfide Compounds

作　　者：张变香[1] 亢永强 史瑞雪[1] 

机构地区：[1]山西大学化学化工学院,太原030006

出　　处：《有机化学》2016年第8期1814-1823,共10页Chinese Journal of Organic Chemistry

基　　金：山西省科技创新(No.2014101011)资助项目~~

摘　　要：近年来芳香杂环硫醚类化合物作为有机合成中间体及药物合成的结构单元,在医药、功能性材料领域被广泛应用,其合成方法的研究也成为当前科研工作的热点之一.综述了近几年芳香杂环硫醚类化合物的合成方法,重点介绍在金属催化下、无金属催化条件下和经由苯炔来制备芳香杂环硫醚的研究进展,并对其部分反应机理做了相应的阐述.Recently, the aromatic heterocyclic sulfide was widely used in medical and functional materials as an intermediate in organic chemistry and a structural unit in drug synthesis. Their synthetic method has become one of the hot research areas. This review summarizes the recent synthetic methods of aromatic heterocyclic thioether, which mainly involves metallic catalyzed and no metal-catalyzed methods, as well as benzene alkyne intermediate method. Some of their synthetic mechanisms were illustrated.

关 键 词：芳香杂环硫醚 金属催化剂 苯炔中间体 

分 类 号：O626[理学—有机化学]