One New 3D Pillared-layer Ag(Ⅰ)-Coordination Framework Based on a Unique 1D Ag2O2 Ribbon： Synthesis,Crystal Structure and Luminescent Properties  

作　　者：王建芳 吴亚盘 伍学谦 文国选 王超 

机构地区：[1]College of Materials and Chemical Engineering,Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials,China Three Gorges University [2]Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education,College of Chemistry & Materials Science,Northwest University

出　　处：《Chinese Journal of Structural Chemistry》2016年第8期1238-1244,共7页结构化学（英文）

基　　金：supported by the NSF of Hubei Province(No.2014CFB277);the Open Foundation of Ministry of Education Key Laboratory of Synthetic and Natural Functional Molecular Chemistry(No.338080057)

摘　　要：A new 3D Ag（I） coordination polymer {[Ag（AZDB）（0.5）（bpe）（0.5）]·H2O}n（1） has been papared by azobenzene-3,3？-dicarboxylicate（H2AZDB）, 1,2-bis（4-pyridyl）ethylene（bpe） and silver salts via hydrothermal method. The compound was fully characterized by single-crystal X-ray diffraction, elemental analyses, infrared spectrum（IR）, powder X-ray diffraction（PXRD） and thermogravimetric analysis（TGA）. The strucrural analysis indicate that compound 1 shows a 3D pillared-layer framework constructed from a unique 1D Ag2O2 ribbon and pyridyl/carboxylicate mixed system, which features a 2-nodal（4, 6）-connected fsc net with a（4^4·6^10·8）（4^4·6^2） topology.Moreover, the photoluminescent properties have also been discussed.A new 3D Ag（I） coordination polymer {[Ag（AZDB）（0.5）（bpe）（0.5）]·H2O}n（1） has been papared by azobenzene-3,3？-dicarboxylicate（H2AZDB）, 1,2-bis（4-pyridyl）ethylene（bpe） and silver salts via hydrothermal method. The compound was fully characterized by single-crystal X-ray diffraction, elemental analyses, infrared spectrum（IR）, powder X-ray diffraction（PXRD） and thermogravimetric analysis（TGA）. The strucrural analysis indicate that compound 1 shows a 3D pillared-layer framework constructed from a unique 1D Ag2O2 ribbon and pyridyl/carboxylicate mixed system, which features a 2-nodal（4, 6）-connected fsc net with a（4^4·6^10·8）（4^4·6^2） topology.Moreover, the photoluminescent properties have also been discussed.

关 键 词：Ag（Ⅰ） coordination polymer 3D pillared-layer framework 1D Ag2O2 ribbon fsc topology 

分 类 号：O641.4[理学—物理化学]