三聚阴离子表面活性剂/阳离子添加剂混合体系的流变行为  

Rheological Behavior of Trimeric Anionic Surfactant/Cationic Additive Mixed Systems

作　　者：周萍萍[1] 席皙 宋冰蕾[1] 裴晓梅[1] 崔正刚[1] 

机构地区：[1]江南大学化学与材料工程学院,食品胶体与生物技术教育部重点实验室,江苏无锡214122

出　　处：《物理化学学报》2016年第9期2309-2317,共9页Acta Physico-Chimica Sinica

基　　金：中央高校基本科研业务专项资金(JUSRP51507,JUSRP51405A);国家自然科学基金(31300486)资助项目~~

摘　　要：表面活性剂的分子结构对蠕虫胶束的形成与性质有着重要影响。本文以十四酸和间苯三酚为起始原料,合成了一种三聚阴离子表面活性剂(2,2′,2′′-(苯基-1,3,5-三(氧))-三-十四酸钠,简写为Ph-TrisC_(14)Na),并通过稳态和动态流变测试,研究了单组分的Ph-TrisC_(14)Na和Ph-TrisC_(14)Na/阳离子添加剂体系的粘弹性质。阳离子添加剂分别为正丁基三甲基溴化铵(C_4TAB),正己基三甲基溴化铵(C_6TAB)和正辛基三甲基溴化铵(C_8TAB)。结果表明,依赖于独特的分子构型,Ph-TrisC_(14)Na分子自身即可形成蠕虫胶束,使溶液表现出明显的粘弹性。阳离子添加剂的加入可进一步优化Ph-TrisC_(14)Na的分子几何结构,促进蠕虫胶束更为快速地生长。随着阳离子添加剂疏水链长的增加,溶液的粘弹性显著增强,体系微结构对添加剂的敏感性也增加。对于50 mmol?L^(-1)的Ph-TrisC_(14)Na溶液来说,在C_8TAB与Ph-TrisC_(14)Na的摩尔比为0.5时,体系的零剪切粘度可达1535 Pa?s,蠕虫胶束的长度则达到4.0-7.5μm。该体系体现出低聚表面活性剂在构筑表面活性剂粘弹溶液方面的优势,可拓展高粘弹性阴离子蠕虫胶束体系的研究范围。Surfactant structure is known to have a significant effect on the formation and properties of wormlike micelles. In the present study, a new trimeric anionic surfactant （sodium 2,2＇,2＂-（benzene-1,3,5-triyltris（oxy）） tritetradecanoate, abbreviated as Ph-TrisC14Na） was synthesized from myristic acid and m-trihydroxybenzene. The viscoelastic properties of single component Ph-TrisC14Na and Ph-TrisC,4Na/cationic additive systems were subsequently investigated by steady state and dynamic rheological measurements, using butyltrimethyl ammonium bromide （C,TAB）, hexyltrimethyl ammonium bromide （C6TAB）, and octyltrimethyl ammonium bromide （CsTAB） as the additives. The results show that the unique molecular structure of Ph-TrisC14Na enables the formation of wormlike micelles when this compound is the sole component of the solution, and generates solutions with significant viscoelasticity. The addition of cationic species further optimizes the molecular geometry of the Ph-TrisC14Na and promotes the rapid growth of wormlike micelles. Additives with longer hydrophobic chains have a marked effect on the viscoelasticity and the microstructure of the mixed solution systems. A 50 mmol·L^-1 Ph-TrisC14Na solution exhibits a zero shear viscosity of 1535 Pa. s together with micelle lengths in the range of 4.0 to 7.5 pm at a C8TAB to Ph-TrisC14Na molar ratio of 0.5. The present system shows the advantage of usJng an olJgomerJc surfactant in viscoelastic surfactant solutions. The information obtaJned from this work should be beneficial with regard to expanding the scope of highly viscoelastic anionic wormlike micellar systems.

关 键 词：三聚阴离子表面活性剂 蠕虫胶束 有机添加剂 分子几何结构 粘弹性 

分 类 号：O647.2[理学—物理化学]