席夫碱在催化剂领域的应用  

Applications of Schiff Base in Catalysis

作　　者：刘秀然[1] 范彩虹[1] 唐关平 许想姣[1] 

机构地区：[1]武汉科技大学化学工程与技术学院,湖北武汉430081

出　　处：《广州化工》2016年第17期8-9,共2页GuangZhou Chemical Industry

基　　金：煤转化与新型炭材料湖北省重点实验室项目:强酸性离子液体分离回收焦化粗苯中噻吩的研究(编号:WKDM201506)

摘　　要：席夫碱主要是指含有亚胺或甲亚胺特性基团(-RC=N-)的一类有机化合物,通常席夫碱是由胺和活性羰基缩合而成,因其在催化领域有着特殊的性能,越来越多的受到化学家们的关注。席夫碱金属配合物催化剂的制备与应用研究一直是十分活跃的领域,已取得了诸多成果。本文介绍了不同类席夫碱金属配合物在催化领域即聚合反应、不对称催化环丙烷化反应、烯烃催化氧化反应、电催化反应四个领域的进展和一些研究成果。Schiff base containing the characteristics of an imine and a methyleneimine group（-RC = N-） is a class of organic compound,which is formed by condensation of amine and reactive carbonyl groups. Because of its special properties in the field of catalysis,more and more attention has been focused on by chemists. The preparation and application of the metalcomplex catalysts of the Schiff base have been a very active field,which has achieved a lot of results. The different types of Schiff base complexes in the polymerization catalysis namely,progress in four areas of catalytic asymmetric cyclopropanation reaction,aspects of the catalytic oxidation of olefins,electric catalysis and some research results were described.

关 键 词：席夫碱 催化剂 应用 

分 类 号：O6[理学—化学]