碱木质素超/亚临界乙醇体系解聚机理研究  

Depolymerization mechanism of alkali lignin in sub-and supercritical ethanol

作　　者：陈梦薇[1] 郭大亮[1,2] 王林芳[1] 薛国新[1] 

机构地区：[1]浙江理工大学纺织纤维材料与加工技术国家地方联合工程实验室,浙江杭州310018 [2]浙江科技学院浙江省废弃生物质循环利用与生态处理技术重点实验室,浙江杭州310023

出　　处：《燃料化学学报》2016年第10期1203-1210,共8页Journal of Fuel Chemistry and Technology

基　　金：国家自然科学基金(31500492);浙江理工大学科研启动基金(14012079-Y);浙江科技学院浙江省废弃生物质循环利用与生态处理技术重点实验室开放基金(2016REWB28)资助~~

摘　　要：采用微型高温高压反应釜,在超/亚临界乙醇体系,进行麦草碱木质素的解聚实验,通过扫描电子显微镜(SEM)、气相色谱/质谱联用仪(GC/MS)及红外光谱仪(FT-IR)对解聚产物进行分析,探讨大分子结构的解聚机理。结果表明,碱木质素在乙醇临界点条件(240℃,7.2 MPa)解聚获得最低残焦得率,数值为16.5%。碱木质素在亚临界乙醇体系解聚过程,碱木质素熔融形成直径1.0-2.0μm的微球分散于乙醇中,结构单体间少量醚键和苯环侧链Cα均裂断裂,形成酚类、酯类、酮类和酸类产物;碱木质素在超临界乙醇体系解聚过程,熔融微球直径明显缩小,解聚时发生大量结构单体间醚键、苯环侧链Cα断裂及酯类产物的二次分解反应,解聚产物中酯类产物含量(11.94%)降低,酚类产物得率(52.14%)提高。The depolymerization process of wheat straw alkali lignin in sub- and supercritical ethanol was investigated with a micro autoclave reactor. The degraded product properties and the depolymerization mechanism of lignin structure were studied by scanning electron microscopy （SEM）, gas chromatography/mass spectrometry （GC/MS） and infrared spectroscopy （FT-IR）. The experimental results show that the minimum residual char yield （16.5%） is obtained at the condition of ethanol supercritical point （240℃, 7.2 MPa）. Under subcritical ethanol conditions, alkali lignin firstly melts and disperses in ethanol as 1.0-2.0 μm diameter of microspheres, then a small amount of ether linkages and benzene ring side chain Cα are broken to form phenols, esters, ketones and acids products. Under supercritical ethanol conditions, the diameter of molten microsphere is significantly reduced, and plenty of ether linkages and benzene ring side chain Cα are continuously broken, meanwhile, the lipid products are subjected to secondary decomposition reaction. The yield of lipid is decreased （11.94%）, while the yield of phenolic products from depolymerization is increased （52.14%）.

关 键 词：碱木质素 超/亚临界乙醇 解聚 

分 类 号：TK6[动力工程及工程热物理—生物能]