甘油气相脱水制备丙烯醛催化剂的研究进展  

Progresses in catalysts for gas phase dehydration of glycerol to acrolein

作　　者：黄亮[1] 徐华龙[1] 沈伟[1] 

机构地区：[1]复旦大学化学系上海市分子催化与功能材料重点实验室复旦大学先进材料实验室,上海200433

出　　处：《石油化工》2016年第9期1021-1030,共10页Petrochemical Technology

基　　金：上海市科学技术委员会资助国际合作项目(14120700700);重点实验室基金项目(14DZ2273900)

摘　　要：以生物质源甘油为原料,通过甘油催化脱水制备丙烯醛是一个非常重要的生物质转化反应。综述了近年来有关甘油气相脱水制备丙烯醛催化剂的研究进展,将催化剂分为分子筛、金属氧化物和复合金属氧化物、杂多酸和磷酸盐3大类进行介绍,指出了在该反应催化剂设计方面面临的问题和挑战,展望了未来的发展趋势。The catalytic dehydration of glycerol to acrolein is an important biomass conversion reaction for the sustainable production of acrolein from bio-based glycerol. This paper summarized the research progresses in catalysts for the gas phase dehydration of glycerol to acrolein. These catalysts were divided into three families,namely molecular sieves,metal oxides and mixed metal oxides, and heteropolyacids and phosphates. In addition, current main problems and challenges in the catalyst design were also discussed. The trend of development for high e？cient catalysts was forecasted.

关 键 词：甘油 丙烯醛 催化脱水 生物质转化 固体酸催化剂 

分 类 号：TQ224.13[化学工程—有机化工]