微波辐射合成N,N-二苯基-3,4,9,10-苝二酰亚胺  

Synthesis of N,N-diphenyl-3,4,9,10-perylene diimide under microwave irradiation

作　　者：王辉[1,2] 

机构地区：[1]宝鸡文理学院化学化工学院,陕西宝鸡721013 [2]陕西省植物化学重点实验室,陕西宝鸡721013

出　　处：《化学研究》2016年第5期557-559,共3页Chemical Research

基　　金：陕西省植物化学重点实验室项目(14JS006);宝鸡文理学院重点项目(ZK12032)

摘　　要：以3,4,9,10-苝四酸酐为原料,无水醋酸锌为催化剂,与苯胺利用微波辐射,合成N,N-二苯基-3,4,9,10-苝二酰亚胺.研究结果表明,在微波辐射下,无水醋酸锌对该反应有较好的催化活性,N,N-二苯基-3,4,9,10-苝二酰亚胺的产率可达60.02%.实验确定了该反应的最终优化条件为:无水醋酸锌的用量为0.5g,微波辐射功率为900 W,辐射时间为50min,反应温度为150℃.N,N-diphenyl-3,4,9,10-perylene diimide was synthesized under microwave irradiation by using perylene anhydride and aniline as raw materials,quinoline as solvent and anhydrous zinc acetate as catalyst.It was confirmed that the anhydrous zinc acetate was an efficient catalyst for this reaction under microwave irradiation to afford corresponding compound with60.02% yields.The optimized reaction condition was as follows：0.5g of amount of anhydrous zinc acetate,900 Wof microwave power,50 min of reaction time,150 ℃ of reaction temperature.

关 键 词：N N-二苯基-3 4 9 10-苝二酰亚胺 微波辐射 苝酐 苯胺 无水醋酸锌 

分 类 号：TQ24[化学工程—有机化工]