金属—金属键化合物的分类及其前景展望  

Classification and prospect of the metal-metal bonding compounds

作　　者：杜利利[1] 王中英[1] 陈照[1] 董青松[1] 

机构地区：[1]河南大学化学化工学院,河南开封475004

出　　处：《化学研究》2016年第5期644-649,共6页Chemical Research

基　　金：河南大学博士科研启动基金(B2015106)

摘　　要：金属-金属键不仅涉及到新型化学键的本质、成键方式等基本理论,而且在催化及材料等方面表现出潜在的应用前景.本文主要从键级方面对金属-金属键化合物进行分类,并对不同键级的金属-金属键化合物通过举例进行详细说明.最后,对金属-金属键化合物的应用前景进行了展望.Synthesis and study of compounds containing metal-metal bonds are one of the most important research fields in chemistry because such compounds not only are related to the fundamental theory about the nature of new chemical bonds,but also found potential applications in catalysis and material science,etc..In this paper,we made classification of the metal-metal bonding compounds according to bond orders,and detail described example about every bond order.Besides,the prospect application of the metal-metal bonding compounds is discussed.

关 键 词：金属-金属键 键级 晶体结构 应用前景 

分 类 号：O614[理学—无机化学]