Er^(3+)掺杂Na_5Lu_9F_(32)单晶体的红外光学特性  

Infrared Optical Properties of Er^(3+)Doped Na_5Lu_9F_(32) Single Crystal

作　　者：汤庆阳[1] 王成[1] 夏海平[1] 何仕楠 江浩川[2] 陈宝玖[3] 

机构地区：[1]宁波大学光电子功能材料重点实验室,浙江宁波315211 [2]中国科学院宁波材料技术与工程研究所,浙江宁波315211 [3]大连海事大学物理系,辽宁大连116026

出　　处：《发光学报》2016年第10期1189-1194,共6页Chinese Journal of Luminescence

基　　金：国家自然科学基金(51472125;51272109);浙江省自然科学基金(Z17E020003);宁波大学王宽诚幸福基金资助项目

摘　　要：采用坩埚下降法成功地生长了Er^(3+)离子掺杂的Na_5Lu_9F_(32)(NLF)单晶体。测定了单晶体在400~2 500nm波段的吸收光谱与2.5~25μm红外波段的透过光谱。Na_5Lu_9F_(32)单晶体在400~7 150 nm宽波段范围具有好的光学透过性,在该波段的透过率达到90%。在透过光谱中几乎观察不到2.7μm中红外波段的吸收,说明单晶体中OH^-离子的含量极低。根据测定的吸收光谱,通过Judd-Ofelt理论计算了Er^(3+)在单晶体中的光学强度参数Ω_t(Ω_2=2.08,Ω_4=2.07,Ω_6=0.75),以及相应的辐射跃迁速率、荧光分支比和荧光寿命。根据Futchbauer-Ladenburg公式估算了样品的发射截面大约分别为1.42×10^(-20)cm^2(~4I_(13/2)→~4I_(15/2))和1.66×10^(-20)cm^2(~4I_(11/2)→~4I_(13/2))。在980 nm半导体激光器(LD)激发下,研究了单晶体的近红外1.5μm与中红外2.7μm的发射光谱特性。Er^（3＋）doped Na_5Lu_9F_（32） single crystal was successfully grown by Bridgman method.The absorption spectra of the single crystal from 400 nm to 2 500 nm and the transmission characteristics from 2.5 μm to 25 μm were measured.Na_5Lu_9F_（32） single crystal possessed high optical transmittance from 400 nm to 7 150 nm wide band,and the transmittance reached to 90%.Almost no absorption of 2.7 μm band was observed.It indicated that the content of OH-ion was very low in the single crystal.The intensity parameters Ωt（ Ω2= 2.08,Ω4= 2.07,Ω6= 0.75） were calculated by using Judd-Ofelt theory based on the absorption spectrum.The radiative transition rates,branching ratios and radiative lifetimes were also obtained.The emission cross sections of the sample were 1.42 ×10^（-20）cm^2（~4I_（13/2）→~4I_（15/2）） and 1.66 × 10^（-20）cm^2（~4I_（11/2）→~4I_（13/2）） estimated by Futchbauer-Ladenburg formula.The emission spectra of 1.5 μm and 2.7 μm band were investigated under 980 nm LD.

关 键 词：ER3+ Na5Lu9F32单晶体 近红外 中红外 

分 类 号：O482.31[理学—固体物理]