2,9-二芳乙烯基-1,10-菲咯啉衍生物的合成研究  

Synthesis of 2,9-Diaryl vinyl-1,10-phenanthroline Derivatives

作　　者：陈南雨 孙圆圆[1] 夏良敏 俞哲健 钱家伟[1] 罗书平[1,2] Nan-yu SUN Yuan-yuan XIA Liang-min YU Zhe-jian QIAN Jia-wei LUO Shu-ping(College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China Yiwu Institute of Science and Technology, Zhejiang University of Technology, Yiwu , Zhejiang 322001, China)

机构地区：[1]浙江工业大学化学工程学院,浙江杭州310014 [2]浙江工业大学义乌科学技术研究院,浙江义乌322001

出　　处：《浙江化工》2016年第10期36-39,共4页Zhejiang Chemical Industry

基　　金：国家自然科学基金(21376222)

摘　　要：设计合成一系列1,10-菲咯啉衍生物,以2,9-二甲基-4,7-二苯基-1,10-菲咯啉与芳基醛为原料,以醋酸酐为溶剂,在酸的催化下,通过Adole缩合反应,合成了7个（E）-2,9-二芳乙烯基-4,7-二苯基-1,10-菲咯啉的衍生物,产率为50%~68%。该合成方法原料易得,操作简单,收率较高,有很好的应用前景。A series of 1,10-phenanthroline derivatives were designed synthesized. In this method, 2,9- dimethyl-4,7-diphenyl-1,10-phenanthroline and aryl aldehyde were used as the starting materials, acetic anhydride was used as the solvent, seven 2,9-（E）-diaryl vinyl-l, 10-phenanthroline derivatives were ob- tained by adole condensation with yield 50% -68 % . The method was of readily available raw materials, simple operation, medium and above yield, apply a wide range of substrates.

关 键 词：1 10-菲咯啉衍生物 adole缩合反应 芳基醛 

分 类 号：O626[理学—有机化学]