ABS树脂废水胶乳浓度对破乳的影响  

Effect of latex concentration in ABS resin wastewater on demulsification

作　　者：罗梦[1,2,3] 宋玉栋[2,3] 郑盛之[2,3,4] 周岳溪[2,3] 何绪文[1] 

机构地区：[1]中国矿业大学(北京)化学与环境工程学院,北京100083 [2]中国环境科学研究院水污染控制技术研究中心,北京100012 [3]中国环境科学研究院环境基准与风险评估国家重点实验室,北京100012 [4]北京师范大学水科学研究院,北京100875

出　　处：《化工学报》2016年第11期4837-4842,共6页CIESC Journal

基　　金：国家水体污染控制与治理科技重大专项资助项目(2012ZX07201-005)

摘　　要：以ABS树脂接枝聚合工段废水为研究对象,聚合氯化铝(PAC)为破乳剂,考察了胶乳浓度对破乳效果的影响。结果表明,不同胶乳浓度下均存在优化的药剂投加量区间,投加量过小或过大均会造成破乳效果不佳。随着胶乳COD浓度由13012 mg·L^(-1)下降至192 mg·L^(-1),单位胶乳COD的优化药剂投加量由6.1~10.8 mg·g^(-1)增加至7.7~13.8 mg·g^(-1),区间向右移动,最佳COD去除率由99.30%下降至91.24%。稀释前后最优单位胶乳COD的药剂投加量提高了40%左右。PAC对ABS树脂废水胶乳的破乳机理以吸附-电性中和为主,随着PAC投加量的增加,胶粒Zeta电位逐渐升高,Zeta电位在-23~13 m V范围内,胶乳可有效破乳。The effect of latex concentration in ABS resin emulsion graft section wastewater on demulsification efficiency was investigated with PAC as demulsifier. The results indicated that there were optimized ranges of reagent dosage in different latex concentrations, as the undersize or oversize dosages could all lead to poor demulsification efficiency. When the latex COD concentration decreased from 13012 mg·L^（-1） to 192 mg·L^（-1）, the optimized ranges of reagent dosage moved right, increasing from 6.1—10.8 mg·g^（-1） to 7.7—13.8 mg·g^（-1）. The optimum COD removal efficiencies dropped from 99.30% to 91.24%. The optimum reagent dosages per latex COD unit increased by about 40%. The demulsification mechanism of latex wastewater by PAC was mainly adsorption-charge neutralization. With increase of PAC dosage, the colloid Zeta potential increased, and the latex could realize demulsification effectively in the range of-23—13 m V.

关 键 词：胶乳废水 破乳 浓度 投加量 聚合物 胶体 乳液 

分 类 号：X783.2[环境科学与工程—环境工程]