尾式苯丙氨酸卟啉锌(Ⅱ)的光谱性质研究  

Synthesis and spectra properites of tailed phenylalanine tetraphenylporphinatozinc(Ⅱ)

作　　者：倪春林[1] 许登清[1] 张昕[1] 王静秋[2] 秦子斌[2] 

机构地区：[1]三峡大学化学化工系,湖北宜昌443000 [2]武汉大学化学与环境科学学院,湖北武汉430072

出　　处：《化学研究与应用》2002年第4期409-411,共3页Chemical Research and Application

基　　金：湖北省教委自然科学基金资助项目

摘　　要：A new tailed phenylalanine tetraphenylporphinatozinc(Ⅱ),5 (p phenylalanineformylmethoxyphenyl) 10,15,20 tri(p chlorophenyl)porphinatozinc(Ⅱ)(Zn) was synthesized.The structure of the compound was characterized by elementary analysis,electric absorption spectra,IR,resonance Raman spectra and 1HNMR.The electronic absorption spectra of axial coordination reactions of Zn with pyridine and in midazole were studied.A new tailed phenylalanine tetraphenylporphinatozinc(Ⅱ),5 (p phenylalanineformylmethoxyphenyl) 10,15,20 tri(p chlorophenyl)porphinatozinc(Ⅱ)(Zn) was synthesized.The structure of the compound was characterized by elementary analysis,electric absorption spectra,IR,resonance Raman spectra and 1HNMR.The electronic absorption spectra of axial coordination reactions of Zn with pyridine and in midazole were studied.

关 键 词：尾式苯丙氨酸卟啉锌(Ⅱ) 合成 光谱 生物大分子 模型化合物 

分 类 号：O614.241[理学—无机化学]