硝酸铋诱导的苯酚单硝基化反应探索  

Protocol for mononitration of phenols with bismuth nitrate

作　　者：叶思源[1] 王晓媛[1] 

机构地区：[1]中国石油大学(华东),山东青岛266580

出　　处：《化学工程与装备》2016年第9期1-2,17,共3页Chemical Engineering & Equipment

摘　　要：在本文中,我们用探索出的一种简单而又高效的方法对取代苯酚进行了选择性的单硝基化。在室温、0.5当量的硝酸铋、以及丙酮作溶剂的条件下,反应能够在没有多硝基副产物生成的情况下,以51%-95%的分离收率生成所需要的单硝基化产物。A simple and effic phenols. The reaction proceed The desired products were isol ient procedure was developed for the selective mononitration of various activated ed smoothly with 0.5 equivalents of Bi（NO3）3·5H2O in acetone at ambient temperature ated in 51 - 95% total yield and essentially no overnitrated compounds were detected.

关 键 词：硝酸铋 单硝基化 苯酚 

分 类 号：O621.251[理学—有机化学]