不同载体铜基催化剂生物质热解气低温变换反应性能研究  

Low Temperature Water-Gas Shift (WGS) Reaction of Biomass Pyrolysis Gas Over Cu Catalyst with Different Supports

作　　者：徐海燕[1,2] 杨延涛[3] 陈高峰[1,2] 雷廷宙[2,4] 何晓峰[1,2] Xu Haiyan Yang Yantao Chen Gaofeng Lei Tingzhou He Xiaofeng(Energy Research Institute Co. Ltd.,Henan Academy of Sciences,Zhengzhou 450008,China Henan Key Lab of Biomass Energy,Zhengzhou 450008,China College of Mechanical and Electrical Engineering,Henan Agricultural University,Zhengzhou 450008,China Henan Academy of Sciences,Zhengzhou 450008,China)

机构地区：[1]河南省科学院能源研究所有限公司,郑州450008 [2]河南省生物质能源重点实验室,郑州450008 [3]河南农业大学机电工程学院,郑州450008 [4]河南省科学院,郑州450008

出　　处：《河南科学》2016年第11期1875-1878,共4页Henan Science

基　　金：国家科技支撑计划项目(2014BAD02B05);河南省科技攻关计划项目(162102210144);河南省基础与前沿技术研究计划项目(132300413218)

摘　　要：采用浸渍法制备了不同载体(ZrO_2、CeO_2、Al_2O_3和ZrO_2/CeO_2)负载的铜基催化剂,对不同载体的催化剂进行了XRD、BET、H2-TPR等表征,并且进一步研究了催化剂对于生物质热解气低温变换反应的催化性能.结果表明,载体对于铜基催化剂低温水煤气变换反应催化性能影响很大,ZrO_2/CeO_2作为载体的催化剂催化效果最佳.在400℃条件下,Cu/ZrO_2/CeO_2催化剂的CO转化率可以达到95%.Cu- based catalysts were prepared with different supports（ZrO2,CeO2,Al2O3 and ZrO2 /CeO2）byimpregnation method. The catalysts were characterized using X-ray diffraction（XRD）,Brunauer-Emmett-Teller（BET）surface area and H2-temperature programmed reduction（H2-TPR）technique. The results indicated thatsupports of the catalysts had great impact on their catalytical performance. Using ZrO2 /CeO2 of the catalyst as supportexhibits had best catalytical performance than the other catalysts. Conversion of CO reached 95% when the reactiontemperature was 400 ℃ on Cu/ZrO2 /CeO2 catalyst.

关 键 词：生物质热解气 铜基催化剂 变换反应 载体 

分 类 号：TK6[动力工程及工程热物理—生物能]